In this paper, the aluminum (Al)
treatment-induced doping effect
on the formation of conductive source-drain (SD) regions of self-aligned
top-gate (SATG) amorphous indium gallium zinc oxide (a-InGaZnO or
a-IGZO) thin-film transistors (TFTs) is systematically investigated.
Average carrier concentration over 1 × 1020 cm–3 and sheet resistance of around 500 Ω/sq result
from the Al reaction doping. It is shown that the doping effect is
of bulk despite the treatment at the surface. The doping process is
disclosed to be a chemical oxidation–reduction reaction, that
generates defects of oxygen vacancies and metal interstitials at the
metal/a-IGZO interface. Both the generated oxygen vacancies and metal
interstitials act as shallow donors, and the oxygen vacancies diffuse
rapidly, leading to the bulk-doping effect. The fabricated SATG a-IGZO
TFTs with the Al reaction-doped SD regions exhibit both high performance
and excellent stability, featuring a low width-normalized SD resistance
of about 10 Ω cm, a decent saturation mobility of 13 cm2/(V s), an off current below 1 × 10–13 A, a threshold voltage of 0.5 V, a slight hysteresis of −0.02
V, and a less than 0.1 V threshold voltage shift under 30 V gate bias
stresses for 2000 s.