Physical and mechanical properties of a novel hydrogen transport membrane

Zhang, Lily Yongjun; Bandopadhyay, Sukumar; Balachandran, U.; Nag, Nagendra

doi:10.1007/s10853-016-0690-1

Cited by 35 publications

(46 citation statements)

References 19 publications

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“…Nevertheless, this approach becomes limiting as full monomer conversions cannot be achieved (166). ATRP in the presence of Cu 0 was later used to generate multiblock glycopolymers with a monomer sequence control (167,168) as well as multiblock copolymers of acrylamides in less than 5 hours (169,170). Photo-ATRP enabled a novel route for exploring polymer composition and microstructure at high monomer conversions with good end group fidelity (93,157,(171)(172)(173)(174).…”

Section: Multiblock Copolymersmentioning

confidence: 99%

Reversible Deactivation Radical Polymerization: State-of-the-Art in 2017

Shanmugam

Matyjaszewski

2018

ACS Symposium Series

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This chapter highlights the current advancements in reversible-deactivation radical polymerization (RDRP) with a specific focus on atom transfer radical polymerization (ATRP). The chapter begins with highlighting the termination pathways for acrylates radicals that were recently explored via RDRP techniques. This led to a better understanding of the catalytic radical termination (CRT) in ATRP for acrylate radicals. The designed new ligands for ATRP also enabled the suppression of CRT and increased chain end functionality. In addition, further mechanistic understandings of SARA-ATRP with Cu 0 activation and comproportionation were studied using model reactions with different ligands and alkyl halide initiators. Another focus of RDRP in recent years has been on systems that are regulated by external stimuli such as light, electricity, mechanical forces and chemical redox reactions. Recent advancements made in RDRP in the field of complex polymeric architectures, organic-inorganic hybrid materials and bioconjugates have also been summarized.

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Section: Multiblock Copolymersmentioning

confidence: 99%

Reversible Deactivation Radical Polymerization: State-of-the-Art in 2017

Shanmugam

Matyjaszewski

2018

ACS Symposium Series

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“…The composition can be varied using either synthetic vinylic glycomonomers or by using functional monomers that can be subsequently modified, post‐polymerisation by functional glycosides. Homopolymers and sequence controlled (multi)block copolymers have been prepared by SET‐LRP and their binding to human C‐type lectin (CTL) DC‐SIGN has been reported . The architecture has been varied by the synthesis of star polymers or through preparation of glycopolymer nanoparticles; either polymeric nanoparticles from self‐assembly in solution or inorganic‐polymer hybrid particles from the grafting of glycopolymers to, or from, the surface of inorganic nanoparticles such as iron oxide .…”

Section: Synthetic Approaches To Covalently‐linked Protein/peptide‐pomentioning

confidence: 99%

Synthesis and Applications of Protein/Peptide-Polymer Conjugates

Wilson

2017

Macromol. Chem. Phys.

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Recent advances in synthetic methodologies have brought us closer than ever to the precision conferred by nature. For example, the control possible in reversible deactivation radical polymerization enables us to design and synthesize macromolecules with unprecedented control over not only the polymer chain ends, but also the side chain functionality. Furthermore, this functionality can be exploited to afford chemical modification of peptides and proteins, with ever‐improving site‐specificity, yielding a range of well‐defined protein/peptide‐hybrid materials. Such materials benefit from the amalgamation of the properties of proteins/peptides with those of the synthetic (macro)molecules in question. Here, the latest developments in the synthesis of functional polymers and their use for preparation of well‐defined protein/peptide‐polymer conjugates will be discussed, with particular attention focused on modulating the stability, efficacy and/or administration of therapeutic peptides.

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“…In the literature, ATRP and RAFT have been used to synthesize different complex polymers containing cationic, anionic or both kinds of functional groups . However, recent reports highlight the possibility of performing polymerizations using a one pot synthesis of block copolymers . These multiblocks have been synthesized in one pot using both Cu catalyzed methods, including those using Cu 0 or SARA ATRP, as well as by RAFT .…”

Section: Introductionmentioning

confidence: 99%

Synthesis of triblock and multiblock methacrylate polymers and self‐assembly of stimuli responsive triblock polymers

Chin

Konkolewicz

et al. 2014

J. Polym. Sci. Part A: Polym. Chem.

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Multisegmented poly(methacrylate)s were synthesized using one pot reversible addition fragmentation chain transfer polymerization. Initially, a series of triblock copolymers were synthesized with different ratios of trimethylsilyl methacrylate, di(ethylene oxide) methacrylate, and oligo(ethylene oxide) methacrylate, and different total polymer molecular weights. Additionally, a polymer containing seven distinct blocks of methacrylic monomers was synthesized in one pot. For the triblock copolymers, the trimethylsilyl group was subsequently hydrolyzed, and the self‐assembly of the triblock copolymer was studied in water, under different pH and thermal conditions. © 2014 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2014, 52, 2548–2555

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Physical and mechanical properties of a novel hydrogen transport membrane

Cited by 35 publications

References 19 publications

Reversible Deactivation Radical Polymerization: State-of-the-Art in 2017

Reversible Deactivation Radical Polymerization: State-of-the-Art in 2017

Synthesis and Applications of Protein/Peptide-Polymer Conjugates

Synthesis of triblock and multiblock methacrylate polymers and self‐assembly of stimuli responsive triblock polymers

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