Phthalocyanine aggregates in the photodynamic therapy: dogmas, controversies, and future prospects

Bunin, Dmitry A.; Martynov, Alexander G.; Gvozdev, Daniil A.; Gorbunova, Yulia G.

doi:10.1007/s12551-023-01129-7

Biophys Rev

2023

DOI: 10.1007/s12551-023-01129-7

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Phthalocyanine aggregates in the photodynamic therapy: dogmas, controversies, and future prospects

Dmitry A. Bunin,

Alexander G. Martynov,

Daniil A. Gvozdev

et al.

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Cited by 10 publications

References 83 publications

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Structural Decoration of Porphyrin/Phthalocyanine Photovoltaic Materials

Mai,

Zhang,

et al. 2024

ChemSusChem

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Porphyrin/phthalocyanine compounds with fascinating molecular structures have attracted widespread attention in the field of solar cells in recent years. In this review, we focus on the pivotal role of porphyrin and phthalocyanine compounds in enhancing the efficiency of solar cells. The review seamlessly integrates the intricate molecular structures of porphyrins and phthalocyanines with their proficiency in absorbing visible light and facilitating electron transfer, key processes in converting sunlight into electricity. By delving into the nuances of intramolecular regulation, aggregated states, and surface/interface structure manipulation, it elucidates how various levels of molecular modifications enhance solar cell efficiency through improved charge transfer, stability, and overall performance. This comprehensive exploration provides a detailed understanding of the complex relationship between molecular design and solar cell performance, discussing current advancements and potential future applications of these molecules in solar energy technology.

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Structural Decoration of Porphyrin/Phthalocyanine Photovoltaic Materials

Mai,

Zhang,

et al. 2024

ChemSusChem

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Molecular brushes with long polyfluorene backbones and polymethacrylic acid side chains: Luminescent properties and self‐organization in solutions

Kaskevich,

Simonova,

Romasheva

et al. 2024

Journal of Polymer Science

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A series of molecular brushes with a polyfluorene (PF) backbone and polymethacrylic acid side chains of varying lengths were prepared by atom transfer radical polymerization. The structure and composition of the synthesized compounds were confirmed by 1H NMR and IR spectroscopy. Effect of the length of the backbone on spectral and conformational parameters of the macromolecules in solutions was analyzed. The grafting density of side chains was about 90%. Spectral methods have been used to determine the dependence of side chain grafting on the luminescent properties of polymer solutions, including quantum yields. It was shown that an optimal length of polymethacrylic acid side chains provides solubility of the polymer brushes. Solutions of PF‐graft‐polymethacrylic acid complexes with the model substance curcumin were investigated. It was established that the molecular brushes containing curcumin form monomolecular micelles. Molecular brushes with zinc phthalocyanine, potential systems for photodynamic, and photothermal therapy, were studied.

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VII Congress of Russian Biophysicists—2023, Krasnodar, Russia

Anashkina,

Rubin,

Gudimchuk

et al. 2023

Biophys Rev

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Phthalocyanine aggregates in the photodynamic therapy: dogmas, controversies, and future prospects

Cited by 10 publications

References 83 publications

Structural Decoration of Porphyrin/Phthalocyanine Photovoltaic Materials

Structural Decoration of Porphyrin/Phthalocyanine Photovoltaic Materials

Molecular brushes with long polyfluorene backbones and polymethacrylic acid side chains: Luminescent properties and self‐organization in solutions

VII Congress of Russian Biophysicists—2023, Krasnodar, Russia

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