This work reports study on the interactions of sulfur-doped fullerenes with halogens and halides (except iodine and iodide) to gain an enlightened vision to such interactions for employing them in possible applications such as sensor and surface adsorption. The ωB97XD DFT code has utilized in this study to obtain adsorption energies in the gas phase and solvent. The energy outcomes showed proper results for adsorptions in both gas and solvent (using PCM model). However, the gas phase interactions are more favorable thermodynamically. The formation of halide complexes releases more energy than the formation of halogen complexes and the strongest interaction is belong to the interactions of disulfur-doped fullerenes with halides. Donor-Acceptor transitions mostly affected by sulfur doping, which made C-S bond as auxiliary tool for the absorption process. The density of states (DOS) plots demonstrated better modification of conductivity properties upon sulfur-doping on fullerene structures. Electron densities and their Laplacians at bond critical points (BCPs) of interaction sites, NCI calculations and further visualizations proved the existence of such these interactions, clearly indeed. It's worthy to point that, in some cases, something like partial functionalization of fullerene have seen and these observations were approved via QTAIM, NCI and energy data. In these cases, the stable and thermodynamically favorable cation of halogenated doped fullerene (along with X3ˉ as counter ion) could be produced from the interaction of double-doped fullerene with two molecular halogens.Please do not adjust margins Please do not adjust margins noncovalent interaction isosurface for one halogen atom in S2F1-DP-X 2 (X=F, Cl, Br) which refer to lack of such interaction in this case (and existing covalent bond). Although, there are much more troughs in negative area of electron density for S2F1-DP-X 2 (X=F, Cl, Br) complexes in figure 6 that could assign to more attractive interactions in those models.