Photosensitivity of polymers based on epoxy-substituted vinylphenylcyclopropanes

Guliev, K. G.; Ponomareva, G. Z.; Guliev, A. M.

doi:10.1134/s1070427206030323

Cited by 8 publications

(4 citation statements)

References 5 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Cyclopropane-containing compounds are known to be effective and relatively safe biocides with high biological activity [13][14][15][16][17][18]. Scientific research aimed at the development of new effective methods of obtaining polymers possessing a complex of predetermined properties retains its relevance.In this connection, it is interesting to study the reactions of radical copolymerization of new binary systems, with specified complex properties, including particularly high biocidal activity of the synthesized copolymer.…”

Section: Introductionmentioning

confidence: 99%

Synthesis of Para-Aminophenyl Cyclopropylmethacrylate and Its Radical Copolymerization With Styrene

Vahabova¹,

Mammadova²,

Guliyev³

2023

AChJ

View full text Add to dashboard Cite

The synthesis of a new monomer para-aminophenyl cyclopropyl methacrylate (APCM) was carried out, its radical copolymerization with styrene was investigated and some regularities of the process were studied. Its radical copolymerizations with styrene were carried out and the resulting copolymers were established in the structures. Based on the IR-NMR and UV spectra, it was found that the copolymerization process of para-aminophenyl cyclopropyl methacrylate proceeds through the double bond, and the substituents, para-aminophenyl cyclopropyl fragment, remain in the side macrochain. The values of the relative activity constants of monomer were determined and the parameters Q and e were calculated according to Alfrey and Pras. The copolymerization constants of the specified compound (r1) with styrene (r2) calculated by the Feinman-Ross method are r1=0.45, r2=0.22, the values of parameters Q and e: Q=0.024 and e=-2.316, respectively. It was revealed that the resulting copolymer has a sufficiently high biomedical activity, which opens the possibility of using this copolymer as a bactericide

show abstract

Section: Introductionmentioning

confidence: 99%

Synthesis of Para-Aminophenyl Cyclopropylmethacrylate and Its Radical Copolymerization With Styrene

Vahabova¹,

Mammadova²,

Guliyev³

2023

AChJ

View full text Add to dashboard Cite

show abstract

“…This explains the great interest of researchers to preparation of new types of photosensitive polymers for microelectronics [2][3][4][5][6][7][8]. We have solved this problem by polymerization of functionally substituted cyclopropyl styrenes [9][10][11].…”

Section: Introductionmentioning

confidence: 99%

COPOLYMERS ON THE BASIS OF (p-CHLOROPHENOXYCARBONYL)-CYCLOPROPYL STYRENE WITH STYRENE AND METHYL METHACRYLATE

Sadygova¹

2022

AChJ

View full text Add to dashboard Cite

The radical copolymerization of (p-chlorophenoxycarbonyl)cyclopropyl styrene with styrene and methyl methacrylate has been carried out. New cyclopropane-containing copolymers have been obtained. It has been established that the synthesized copolymers due to peculiarities of their structure and polyfucntionality, namely with content of carbonyl and cyclopropane groups sensitive to UV irradiation in the macromolecule have photosensitivity. The constant values of relative activity of monomers have been determined and Q-e parameters on Alfrey and Price have been calculated. The copolymerization constants of this compound (r1) with styrene and methyl methacylate (r2), calculated on Fineman-Ross method are: r1 = 1.1 and1.05, but r2 = 0.56 and 0.48, respectively; Q and e parameters values: Q1 = 3.1 and 2.4, e1 = –1.4 and –0.8, respectively. The photochemical structuring has been investigated and it has been shown that the structuring process proceeds due to of cyclopropane ring opening and carbonyl group. The composition and structure of these copolymers have been established and their some characteristics (heat resistance, hardness, adhesive strength, water absorption) have been investigated. The structuring process has been also studied and it has been established that the synthesized copolymer has relatively high photosensitivity (50–55 cm2J-1)

show abstract

“…It was known that the cyclopropanecontaining compounds are effective and relatively safe biocidal substances. In considering pseudo-unsaturated nature of cyclopropane ring and high biological activity of many compounds cyclopropane series [5][6][7][8], the present article sets an aim to synthesize a new monomer 1-(p-vinylphenyl)-2diethylamino-methyl cyclopropane (VPhDEC) and its sopolymerization with methylmetacrylate as well as research into bactericide properties of obtained sopolymers of different composition.…”

Section: Introductionmentioning

confidence: 99%

Synthesis of 1-(P-Vinylphenyl)-2- Diethylaminomethylcyclopropane and Its Radical Copolymerization With Methyl Methacrylate

Sadygova¹

2021

Chemical Problems

View full text Add to dashboard Cite

The radical copolymerization of 1-(p-vinylphenyl)-2-diethylaminomethylcyclopropane with methyl methacrylate was carried out and some regularities of the process examined. Values of constants of relative activity of monomers were determined and Q-e parameters calculated on Alfrey and Price. Copolymerization constants of this compound (r1) with methyl methacrylate (r2), calculated on the FinemanRoss method, are as follows: r1 = 0.95, r2 = 0.33, Q and e parameter values: Q1 = 1.80, e1 = -0.72, respectively. The photochemical structuring of the copolymer was studied. It was established that the obtained copolymer has a sufficiently high biomedical activity which opens up the possibility of its using as bactericides and fungicides

show abstract

Photosensitivity of polymers based on epoxy-substituted vinylphenylcyclopropanes

Cited by 8 publications

References 5 publications

Synthesis of Para-Aminophenyl Cyclopropylmethacrylate and Its Radical Copolymerization With Styrene

Synthesis of Para-Aminophenyl Cyclopropylmethacrylate and Its Radical Copolymerization With Styrene

COPOLYMERS ON THE BASIS OF (p-CHLOROPHENOXYCARBONYL)-CYCLOPROPYL STYRENE WITH STYRENE AND METHYL METHACRYLATE

Synthesis of 1-(P-Vinylphenyl)-2- Diethylaminomethylcyclopropane and Its Radical Copolymerization With Methyl Methacrylate

Contact Info

Product

Resources

About