Photoredox/Cu‐Catalyzed Decarboxylative C(sp3)−C(sp3) Coupling to Access C(sp3)‐Rich gem‐Diborylalkanes
Mingming Huang,
Huaxing Sun,
Florian Seufert
et al.
Abstract:gem‐Diborylalkanes are highly valuable building blocks in organic synthesis and the pharmaceutical chemistry due to their ability to participate in multi‐step cross‐coupling transformations, allowing for the rapid generation of molecular complexity. While progress has been made in their synthetic metholodology, the construction of β‐tertiary and C(sp3)‐rich gem‐diborylalkanes remains a synthetic challenge due to substrate limitations and steric hindrance issues. An approach is presented that utilizes synergist… Show more
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