2008
DOI: 10.1063/1.2830985
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Photoluminescence study of ZnCdO alloy

Abstract: The photoluminescence (PL) properties of ZnCdO alloy are investigated at various temperatures. Each PL profile contains four distinct peaks: P1, P2, P3, and P4. Peak P4 is due to free-excitonic recombination. The temperature mapping of the P3 peak position shows an S-shaped shift similar to the InGaN system due to the inhomogeneous distribution of Cd in ZnCdO alloy. The peak P2 is attributed to the phonon replica of the localized excitonic emission (P3). The linewidth of the photoluminescence profiles of the Z… Show more

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Cited by 39 publications
(21 citation statements)
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“…29,30 As temperature increases further, the carriers in lower lying localized states are thermally activated to occupy higher energy localized states and gradually approach to an equilibrium energy distribution, which leads to a decrease of FWHM of PL emission band 29 in the temperature range of 100 K < T < 200 K. At sufficiently high temperatures (beyond 200 K), the FWHM increases again in accordance with the thermal broadening of PL line shape. 31 However, in unalloyed semiconductors with the absence of carrier localization, the FWHM increases monotonically with temperature which can be expressed by the following relation: 32 CðTÞ ¼ Cð0Þ þ aT þ b=½expð hx LO =k B TÞ À 1;…”
Section: Resultsmentioning
confidence: 99%
“…29,30 As temperature increases further, the carriers in lower lying localized states are thermally activated to occupy higher energy localized states and gradually approach to an equilibrium energy distribution, which leads to a decrease of FWHM of PL emission band 29 in the temperature range of 100 K < T < 200 K. At sufficiently high temperatures (beyond 200 K), the FWHM increases again in accordance with the thermal broadening of PL line shape. 31 However, in unalloyed semiconductors with the absence of carrier localization, the FWHM increases monotonically with temperature which can be expressed by the following relation: 32 CðTÞ ¼ Cð0Þ þ aT þ b=½expð hx LO =k B TÞ À 1;…”
Section: Resultsmentioning
confidence: 99%
“…In spite of that, ternary ZnCdO is regarded as an ideal candidate for the active layer in a quantum well of ZnO-based devices. However, very few reports on ZnCdO have been published up to now [12][13][14]. Therefore, the fundamental properties of ZnCdO alloy such as bandgap engineering, thermal stability of heterointerface, index of refraction and crystal growth conditions are surely requested for more application in optoelectronic devices.…”
Section: Introductionmentioning
confidence: 99%
“…Moreover, it is commercially available with advantages of low cost, nontoxicity, high chemical and thermal stability and high radiation hardness [8]. CdO is the most promising candidate for narrowing the band gap of ZnO and stretching the emission spectrum from UV to the visible spectral region [9]- [12].…”
Section: Introductionmentioning
confidence: 99%