2010
DOI: 10.1002/pola.24264
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Photoinitiated alternating copolymerization of dialkyl maleates and fumarates with vinyl ethers

Abstract: A systematic study of the free radical photoinitiated alternating crosslinking copolymerizations of dialkyl maleates and furmarates with multifunctional vinyl ethers was carried out. The photocopolymerizations were fast and highly efficient when carried out using a variety of a-cleavage photoinitiators. The effects of the structures of the both the unsaturated esters and the vinyl ether monomers were examined. Dialkyl maleates were observed to be more reactive than the corresponding fumarate esters. The photop… Show more

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Cited by 6 publications
(9 citation statements)
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“…Indeed, in the literature, it was reported for this maleate product a chemical shift for the two protons of the double bond of 6.24 ppm 23,24 whereas the chemical shift for the fumarate product was 6.85 ppm. 24,25 As the cis and trans -products did not show the same reactivity in copolymerization, 2,10 a control of the reaction time is essential.…”
Section: Resultsmentioning
confidence: 99%
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“…Indeed, in the literature, it was reported for this maleate product a chemical shift for the two protons of the double bond of 6.24 ppm 23,24 whereas the chemical shift for the fumarate product was 6.85 ppm. 24,25 As the cis and trans -products did not show the same reactivity in copolymerization, 2,10 a control of the reaction time is essential.…”
Section: Resultsmentioning
confidence: 99%
“… 8,9 Under UV-curing, maleates usually showed a faster reactivity than the more thermodynamically stable fumarates. 2 Nonetheless, the opposite effect was observed 10 and another study will be dedicated to the comparison of their kinetics. In comparison to the common (meth)acrylic systems, their polymerization is less sensitive to oxygen.…”
Section: Introductionmentioning
confidence: 96%
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“…It is noteworthy that dialkyl maleates are among the most applicable chemicals which have been are used in production of copolymers, inhibitors in industrial curing, coatings with special properties and their medicinal and pharmaceutical importance . In the following, by replacing 1,2‐diamines 1 a‐c with amines 7 a‐c , we got diastereoselectively access to dialkyl 2‐amino‐3‐thiomaleates ( Z )‐ 8 a‐f (Scheme ).…”
Section: Resultsmentioning
confidence: 99%