Photoexcitation of Distinct Divalent Palladium Complexes in Cross‐Coupling Amination Under Air
Rajesh Kancherla,
Krishnamoorthy Muralirajan,
Sayan Dutta
et al.
Abstract:The development of metal complexes that function as both photocatalyst and cross‐coupling catalyst remains a challenging research topic. So far, progress has been shown in Pd0 excited‐state transition metal catalysis for the construction of C–C bonds where the oxidative addition of alkyl/aryl halides to zero‐valent palladium (Pd0) is achievable at room temperature. In contrast, the analogous process with divalent palladium (PdII) is uphill and endothermic. For the first time, we report that divalent PdII can a… Show more
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