Photoemission of benzene on Os (0001 ): A synchrotron radiation study

Risk factors for unplanned transfer to intensive care within 24 hours of admission from the emergency department in an integrated healthcare system

“…The most salient structural feature is the remaining Rh 3 , which is face‐capped by a toluene ligand in the unprecedented μ 3 ‐η 1 :η 1 :η 1 coordination mode. This coordination geometry of benzene has been observed on many metal surfaces, such as Rh (111),9 Os (0001),10 and Ru (0001) 11. A closely related molecular system with C 3 v (σ v ) is also known for the [{(C 5 Me 5 )Ru} 3 (μ‐H) 3 (μ 3 ‐η 3 :η 3 ‐C 6 H 6 )] 2+ ion, however, the interaction of the C 6 ring to the triangular metal framework is not symmetrical 12.…”

The structure, ordering, and chemistry of molecular overlayers on Rh(111) and Rh(100) single crystal surfaces: A vibrational spectroscopic and LEED crystallographic study

“…the 7r shift. The surface symmetry of benzene was also deduced to be sixfold on R.h(111) [171,170] and threefold on Pt(I11) [185], !r(I11) [186], and Os(OOI) [187] surfaces, in contrast to the LEED calculation. It may be that ARUPS is not sensitive enough to determine the distortion observed on the Rh(111) surface.…”

The Molecular Structure of [Os3Rh4(μ3‐η1:η1:η1‐C6H5CH3)(CO)13]: A Face‐Capping Bonding Mode for Arenes in Organometallic Clusters

“…The most salient structural feature is the remaining Rh 3 , which is face-capped by a toluene ligand in the unprecedented m 3 -h 1 :h 1 :h 1 coordination mode. This coordination geometry of benzene has been observed on many metal surfaces, such as Rh (111), [9] Os (0001), [10] and Ru (0001). [11] A closely related molecular system with C 3v (s v ) is also known for the [{(C 5 Me 5 )Ru} 3 (m-H) 3 (m 3 -h 3 :h 3 -C 6 H 6 )] 2+ ion, however, the interaction of the C 6 ring to the triangular metal framework is not symmetrical.…”