Abstract:A model for simulating photoelectron spectra of the triatomic van der Waals complexes containing stable atomic anion and diatomic molecule is proposed and applied to the Cl(-)...H(2) and Cl(-)...D(2) anions. The model assumes adiabatic separation of the electronic and nuclear motions and localization of the photodetachment act at the atomic chromophore. Under these approximations, the electronic transition dipole moment matrix elements are evaluated using the atoms-in-molecule approach and explicit expressions… Show more
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