Photoelectrochemical and electrochemical CO<sub>2</sub>reduction to formate on post-transition metal block-based catalysts

Zhang, Qixing; Wang, Zhongke; He, Han; Wang, Juan; Zhao, Ying; Zhang, Xiaodan

doi:10.1039/d3se00103b

Cited by 3 publications

(1 citation statement)

References 129 publications

(255 reference statements)

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“…In this part, we will briefly discuss the major challenges first and then we summarize the opportunities for the future developments in the field; considering that a significant number of review papers were published on water splitting and CO 2 reduction, − we will restrict ourselves with issues associated with halide perovskites applications.…”

Section: Challenges and Opportunities For Pec Applications Of Mhpsmentioning

confidence: 99%

Halide Perovskites for Photoelectrochemical Water Splitting and CO₂ Reduction: Challenges and Opportunities

Bienkowski,

Solarska,

Trinh

et al. 2024

ACS Catal.

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Photoelectrochemical water splitting and CO2 reduction provide an attractive route to produce solar fuels while reducing the level of CO2 emissions. Metal halide perovskites (MHPs) have been extensively studied for this purpose in recent years due to their suitable optoelectronic properties. In this review, we survey the recent achievements in the field. After a brief introduction to photoelectrochemical (PEC) processes, we discussed the properties, synthesis, and application of MHPs in this context. We also survey the state-of-the-art findings regarding significant achievements in performance, and developments in addressing the major challenges of toxicity and instability toward water. Efforts have been made to replace the toxic Pb with less toxic materials like Sn, Ge, Sb, and Bi. The stability toward water has been also improved by using various methods such as compositional engineering, 2D/3D perovskite structures, surface passivation, the use of protective layers, and encapsulation. In the last part, considering the experience gained in photovoltaic applications, we provided our perspective for the future challenges and opportunities. We place special emphasis on the improvement of stability as the major challenge and the potential contribution of machine learning to identify the most suitable formulation for halide perovskites with desired properties.

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Section: Challenges and Opportunities For Pec Applications Of Mhpsmentioning

confidence: 99%

Halide Perovskites for Photoelectrochemical Water Splitting and CO₂ Reduction: Challenges and Opportunities

Bienkowski,

Solarska,

Trinh

et al. 2024

ACS Catal.

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Achieving Higher Efficiency on N₂ Reduction Reaction through Mo‐ and Bi‐Based Active Sites for Sustainable Photoelectrochemical Ammonia Production

Jesudass,

Jo,

Kim

et al. 2024

Solar RRL

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Hydrogen energy from water splitting is considered the highly anticipated modern energy resource; however, storage and transportation require complex and high‐cost facilities, which argue about the efficiency of hydrogen fuel compared to conventional fuels. Thereby, ammonia (NH3), which is a liquid at ambient conditions, promises a lower cost of storage and transportation, but the production of ammonia imposes difficulties with selectivity and efficiency over several products and, notably, hydrogen evolution reaction. Among several methods combining the advantages of electrochemical and photocatalytic properties, the photoelectrochemical (PEC) method is destined to improve the efficiency of ammonia production from N2 reduction reaction (NRR). Because of the multistep NRR process, enormous negative potentials, and poor reaction kinetics, the activity and selectivity of NRR are severely compromised. Therefore, Mo‐ and Bi‐based catalysts are rationally developed to promote the activity and selectivity of NRR processes. Combining the benefits of Mo‐ and Bi‐based catalysts is anticipated to result in highly effective PEC NRR activity. This review is predicted to emphasize the role and characteristics of PEC NRR and the value of Mo and Bi catalysts in raising ammonia's activity and selectivity.

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Amine-functionalized polymer membrane for the electrochemical reduction of CO₂ to hydrocarbons

Kumar,

Aeshala,

Palai

2024

Sustainable Energy Fuels

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Photoelectrochemical and electrochemical CO₂reduction to formate on post-transition metal block-based catalysts

Abstract: The current status, challenges, and future opportunities of post-transition metal block-based catalysts for photoelectrochemical/electrochemical CO2 reduction are summarized, which is expected to provide readers with an overview of this field.

Cited by 3 publications

References 129 publications

Halide Perovskites for Photoelectrochemical Water Splitting and CO₂ Reduction: Challenges and Opportunities

Halide Perovskites for Photoelectrochemical Water Splitting and CO₂ Reduction: Challenges and Opportunities

Achieving Higher Efficiency on N₂ Reduction Reaction through Mo‐ and Bi‐Based Active Sites for Sustainable Photoelectrochemical Ammonia Production

Amine-functionalized polymer membrane for the electrochemical reduction of CO₂ to hydrocarbons

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Photoelectrochemical and electrochemical CO2reduction to formate on post-transition metal block-based catalysts

Abstract: The current status, challenges, and future opportunities of post-transition metal block-based catalysts for photoelectrochemical/electrochemical CO2 reduction are summarized, which is expected to provide readers with an overview of this field.

Cited by 3 publications

References 129 publications

Halide Perovskites for Photoelectrochemical Water Splitting and CO2 Reduction: Challenges and Opportunities

Halide Perovskites for Photoelectrochemical Water Splitting and CO2 Reduction: Challenges and Opportunities

Achieving Higher Efficiency on N2 Reduction Reaction through Mo‐ and Bi‐Based Active Sites for Sustainable Photoelectrochemical Ammonia Production

Amine-functionalized polymer membrane for the electrochemical reduction of CO2 to hydrocarbons

Contact Info

Product

Resources

About

Photoelectrochemical and electrochemical CO₂reduction to formate on post-transition metal block-based catalysts

Halide Perovskites for Photoelectrochemical Water Splitting and CO₂ Reduction: Challenges and Opportunities

Halide Perovskites for Photoelectrochemical Water Splitting and CO₂ Reduction: Challenges and Opportunities

Achieving Higher Efficiency on N₂ Reduction Reaction through Mo‐ and Bi‐Based Active Sites for Sustainable Photoelectrochemical Ammonia Production

Amine-functionalized polymer membrane for the electrochemical reduction of CO₂ to hydrocarbons