Abstract:CO and H 2 evolution from renewable and abundant biomass represent a sustainable way, but is challenged to be produced under mild conditions. Herein, we propose to produce CO and H 2 from biomass via a divided photoelectrochemical (PEC) cell at room temperature. Nitrogen doped tungsten trioxide (N-WO 3 ) photoanode reforms biopolyols to CO and H + , and platinum cathode reduces H + to H 2 , achieving CO evolution rate of 45 mmol m À 2 h À 1 (> 75 % gas selectivity) and H 2 evolution rate of 237 mmol m À 2 h À … Show more
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