A binary mixture of spherical macromolecules in solution is analysed by a quasi-elastic light-scattering experiment for low intensity levels (less than one photoelectron per coherence time). In this situation, the Laplace transform, Qs), of the distribution of the time interval between two consecutive photoelectrons has been measured. The results have been compared with those obtained by the measurement of the second-order correlation function, g''l(r), for the same exoerimental conditions.