“…As far as the energy and the probability of emission and phonon transitions can be different and depend on temperature, the total effect observed can be rather complicated. That is responsible for the large values of the temperature coefficient of E g , dE g /dT, equal to ± ±(6 to 9) Â 10 ± ±4 eV/K (Table 1) which appears to be essentially different from the analogous coefficient of single-crystal CuInS 2 data, À0.7 Â 10 ± ±4 eV/K [28]. Herewith, it is close to the value of dE g /dT for the binary ana-536 L. I. Gurinovich, V. S. Gurin, V. A. Ivanov, I. V. Bodnar, A. P. Molochko, and N. P. Solovej Fig.…”