2000
DOI: 10.1039/b004079g
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Photodissociation of p-ethyl- and p-(α-hydroxyethyl)toluene in solution

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Cited by 2 publications
(2 citation statements)
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“…This is similar to the reported rate constants for the formation of the T 1 of benzene and toluene. Furthermore, laser flash photolysis of p-methylphenylethanol has been reported to produce its T 1 , which has an absorption between 300 and 400 nm and a lifetime of 2 ms. [40] Because 3 and 4 have similar S 0 absorption, but 4 is not as an efficient sensitizer as 3, we propose that the smaller rate constant for intersystem crossing in 4 causes it to be both a singlet and triplet sensitizer for azidoadamantane. Furthermore, the shorter lifetime of the T 1 of 2 causes it to be a less effective sensitizer than 1.…”
Section: Laser Flash Photolysismentioning
confidence: 87%
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“…This is similar to the reported rate constants for the formation of the T 1 of benzene and toluene. Furthermore, laser flash photolysis of p-methylphenylethanol has been reported to produce its T 1 , which has an absorption between 300 and 400 nm and a lifetime of 2 ms. [40] Because 3 and 4 have similar S 0 absorption, but 4 is not as an efficient sensitizer as 3, we propose that the smaller rate constant for intersystem crossing in 4 causes it to be both a singlet and triplet sensitizer for azidoadamantane. Furthermore, the shorter lifetime of the T 1 of 2 causes it to be a less effective sensitizer than 1.…”
Section: Laser Flash Photolysismentioning
confidence: 87%
“…This is similar to the reported rate constants for the formation of the T 1 of benzene and toluene. Furthermore, laser flash photolysis of p ‐methylphenylethanol has been reported to produce its T 1 , which has an absorption between 300 and 400 nm and a lifetime of 2 µs …”
Section: Laser Flash Photolysismentioning
confidence: 99%