1996
DOI: 10.1016/1010-6030(95)04174-5
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Photodechlorination of octachlorodibenzo-p-dioxin and octachlorodibenzofuran in alkane solvents in the absence and presence of triethylamine

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Cited by 20 publications
(16 citation statements)
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“…The photolysis rate constants and half-lives ( t 1/2 ) of 18 irradiated PFDDs are listed in Table . As anticipated, the congeners with higher fluorination have lower rate constants in general, similar to the previous study on PCDDs photolysis …”
Section: Resultssupporting
confidence: 89%
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“…The photolysis rate constants and half-lives ( t 1/2 ) of 18 irradiated PFDDs are listed in Table . As anticipated, the congeners with higher fluorination have lower rate constants in general, similar to the previous study on PCDDs photolysis …”
Section: Resultssupporting
confidence: 89%
“…As anticipated, the congeners with higher fluorination have lower rate constants in general, similar to the previous study on PCDDs photolysis. 34 Compared with PCDDs, the photolysis half-lives of PFDD isomers were different. Taking for example 2,3,7,8-TeFDD, its photodegradation half-life (t 1/2 ) was 0.84 h, and the corresponding t 1/2 value of 2,3,7,8-TeCDD was 7.7 h in the alkane/alcohol mixture solvent.…”
Section: ■ Materials and Methodsmentioning
confidence: 99%
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“…Previous work with 18 suggests that both states are reactive in the photodechlorination reactions, but no investigations of aryl-ether cleavage were performed. 19 Because of the increase in spin-orbit coupling, all chlorinated dibenzo [1,4]dioxins are expected to have shorter singlet and triplet state lifetimes than the parent system.…”
Section: Photoproduct Studiesmentioning
confidence: 99%