1993
DOI: 10.1007/bf03040832
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Photocyclization of arylethylenes: Mechanism and scope of the reactions

Abstract: The photocyclization of three structural types of arylethylenes is systematically investigated in order to provide new pathways to regiospecifically substituted and/or partially hydrogenated polycyclic aromatic hydrocarbons. The scope of the photoformation of acenaphthenes from ~t-arylotefins, in amine solutions, is discussed: when the double bond is acyclic, only the naphthyl and the pyrenyl derivatives are photoreactive, but when the double bond is in a cycle, all the compounds which lead to the trans double… Show more

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