1989
DOI: 10.1021/ma00191a004
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Photocopolymerizations of electron-rich olefins with electron-poor olefins by irradiation of their EDA complexes

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Cited by 46 publications
(19 citation statements)
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“…With regards to UV‐curing coatings technologies, donor‐acceptor chemistry has been reported as a feasible alternative to acrylate‐based systems. With donor‐acceptor chemistry, free‐radical induced alternating photocopolymerization is achieved by mixing an electron‐deficient vinyl group with an electron‐rich vinyl group 36. The benefits of using donor‐acceptor chemistry include high flexibility in polymer backbone design, low toxicity of monomers, and comparable cure times to acrylate systems.…”
Section: Introductionmentioning
confidence: 99%
“…With regards to UV‐curing coatings technologies, donor‐acceptor chemistry has been reported as a feasible alternative to acrylate‐based systems. With donor‐acceptor chemistry, free‐radical induced alternating photocopolymerization is achieved by mixing an electron‐deficient vinyl group with an electron‐rich vinyl group 36. The benefits of using donor‐acceptor chemistry include high flexibility in polymer backbone design, low toxicity of monomers, and comparable cure times to acrylate systems.…”
Section: Introductionmentioning
confidence: 99%
“…[7 -10] The photochemistry of quinoid monomers is an interesting topic: depending on the reaction partner, the triplet state of quinoid monomers can abstract hydrogen atoms, [3,6] react by electron transfer [4,5] or lead to the collapse of an exciplex into a biradical/zwitterion. [9,11] Each of these mechanisms has been forwarded as the cause of photoinitiation. Experimental evidence and kinetic considerations lead us to favour a mechanism based on radical ions following electron transfer.…”
Section: Introductionmentioning
confidence: 99%
“…Recently, Hall et al [7][8][9][10][11] reported that certain donor/acceptor monomer combinations can polymerize upon exposure to light in the absence of added photoinitiator.…”
Section: Introductionmentioning
confidence: 99%