“…In 1992, the family of biradical compounds was first explored by Toda and Tanaka [9]. During the past years, various types of organic photochromic compounds have aroused lots of interests because of their potential applications as photoswitchable molecular devices, optical memory storage media, as well as multi-color display [10][11][12][13][14][15][16][17]. For practical applications, some groups try to modulate the photochromic properties of diarylethenes, which has recently been reported.…”
“…In 1992, the family of biradical compounds was first explored by Toda and Tanaka [9]. During the past years, various types of organic photochromic compounds have aroused lots of interests because of their potential applications as photoswitchable molecular devices, optical memory storage media, as well as multi-color display [10][11][12][13][14][15][16][17]. For practical applications, some groups try to modulate the photochromic properties of diarylethenes, which has recently been reported.…”
“…The colour returned to white when they were transferred indoors. The colour-changing phenomenon was evident and sensitive and could be ascribed to the reversible change of chemical structure in the spirooxazine compound (Partington and Towns 2014).…”
To develop a smart, colour-changing wood material, photochromic microcapsules were incorporated into coatings while painting veneered plywood. The properties of microcapsules and coatings were investigated. The colour-changing behaviour of the photochromic wood material in response to sunlight exposure was evaluated. The microcapsules exhibited sensitive colour-changing function and had good thermal stability. The prepared photochromic wood material spontaneously altered its appearance from the veneer colour to a blue colour following intensity changes of the sunlight exposure on the sample. The incorporation of microcapsules had no obvious effect on coating adhesion, but it obviously reduced coating wearability. With the microcapsule content increasing from 2.5% to 10% (of the coating weight), the colour difference (ΔE) of photochromic wood stimulated by sunlight linearly increased from 7.45 to 21.58. The performance of the prepared photochromic wood material can be adjusted by controlling the addition amount of microcapsules.
“…Among the photochromic dyes, spirooxazines have been extensively investigated due to their ability to impart intense photocoloration in appropriate application media, excellent fatigue resistance and ease of synthesis [9][10][11][12][13][14]. Spirooxazines are generally colorless, however, they become intensely colored when exposed to UV light, and once again become colorless when the light source is removed.…”
Photochromic fabric can change color when exposed to a certain light wavelength. The fabric can reversibly restore to its original color after the light disappears. In this study, two spirooxazines with photochromic properties, i.e., N- ,4] oxazine] (Spirooxazine B), were synthesized. The spirooxazines were characterized by Fourier transform infrared (FTIR) and ultraviolet (UV) spectrophotometers. Spirooxazines A and B were used to dye cotton fabrics under ultrasonic irradiation. The results show that cotton fabric dyed with Spirooxazine B has excellent photochromic properties, and better fading time and fatigue resistance.
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