Photochromic Ln-MOFs: A Platform for Metal-Photoswitch Cooperativity
Corey R. Martin,
Grace C. Thaggard,
Ingrid Lehman-Andino
et al.
Abstract:Optoelectronic devices based on lanthanide-containing materials are an emergent area of research due to imminent interest in a new generation of diode materials, optical and magnetic sensors, and ratiometric thermometers. Tailoring material properties through the employment of photo-or thermochromic moieties is a powerful approach that requires a deep fundamental understanding of possible cooperativity between lanthanide-based metal centers and integrated switchable units. In this work, we probe this concept t… Show more
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