Photochemical replacement of benzene in the tetramethylcyclopentadienyl complex of iron, [η-C5Me4H)Fe(η-C6H6)]+

Loginov, Dmitry A.; Baravi, I. D.; Аrtyushin, О. I.; Starikova, Z. A.; Petrovskii, P. V.; Kudinov, Alexander R.

doi:10.1007/s11172-010-0240-y

Cited by 9 publications

(2 citation statements)

References 13 publications

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“…[29][30][31] Starting from I, some cationic triple-decker compounds [(Cp*M)(Cp R M 0 )(Z 5:5 -P 5 )] + (M, M 0 = Fe, Ru; Cp R = Cp, Cp*), containing group 8 elements, have been reported. 32,33 Furthermore, mixed-metal lanthanideiron compounds with a cyclo-P 5 middle-deck 26 and triple-decker complexes consisting of I and a [M(CO) 3 ] fragment (M = Cr, Mo, W) are known. 34 Herein, we report the synthesis of the first neutral complexes with a functionalized P 5 middle-deck under mild conditions.…”

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Triple-decker sandwich complexes with a bent cyclo-P₅ middle-deck

et al. 2016

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New types of triple-decker complexes with an organo-substituted P middle-deck were synthesized by the reaction of [Cp*Fe(η-PR)] (1a: R = CHSiMe; 1b: R = NMe) with halogeno-bridged transition metal dimers [Cp'''MX] (M = Cr, Fe, Co, Ni; X = Cl, Br). By oxidation of [(Cp*Fe)(Cp'''Co)(μ,η-PCHSiMe)] 2a with [CpFe][PF], the cationic complex [(Cp*Fe)(Cp'''Co)(μ,η-PCHSiMe)] was isolated. The electronic structure of the synthesized complexes was elucidated by DFT calculations.

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Triple-decker sandwich complexes with a bent cyclo-P₅ middle-deck

et al. 2016

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“…5 Development of this method al lowed one to obtain half sandwich, sandwich, and triple decker complexes, as well as metallacarboranes and clus ters containing the CpFe fragment. [6][7][8][9][10][11] The Cb*Co (Cb* = C 4 Me 4 ) and CpFe fragments are isolobal, which allows one to expect similar chemical behavior for their derivatives. 12 The iodide complex Cb*Co(CO) 2 I (1) was synthesized by the transfer of the cyclobutadiene ligand from the nickel halide complexes [Cb*NiX 2 ] 2 (X = Cl, I).…”

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confidence: 99%