Photochemical Reactivity of Halofuran and Halothiophene Derivatives with Benzimidazole

D’Auria, Maurizio

doi:10.3987/com-91-5730

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Methods 3: Substitution By Alkyl Aryl and Substituted Alkyl1

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1991

2011

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Cited by 8 publications

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“…[2] When 1-methyl-1H-benzimidazole (91) is treated with excess aromatic aldehyde, acyl halide, and triethylamine in acetonitrile solution the ultimate heterocyclic product is the secondary alcohol 92. [360] Photochemical 2-arylations of benzimidazoles use the common phenyl radical sources N-nitrosoacetanilide, diazoaminobenzene, and benzoyl peroxide. [358,359] 1H-Benzimidazole couples under photochemical conditions to give a mixture of products linked through C2 of one molecule and C4 or C5 of the other, although coupling with 2-acetyl-5-iodothiophene occurs only in the 4-position.…”

Section: Methods 3: Substitution By Alkyl Aryl and Substituted Alkylmentioning

confidence: 99%