Abstract:The reaction between 1-phenylethyl peroxy radicals and 1-phenyl ethanol, benzyl alcohol and cumyl alcohol has been studied at T = 55°C. The rate coefficients of the hydrogen abstraction reactions for the three alcohols are 18.7 f 2.7, 17.8 f 1.9 and 4.8 f 0.5 M-' s-', respectively. In the case of 1-phenyl ethanol experiments were carried out at T = 25 and 40°C as well, resulting in rate coefficients of 7.3 f 0.7 and 10.5 f 0.9 M-' s-', while the energy of activation -taking into consideration also the data of … Show more
ChemInform Abstract The photochemical generation of the peroxy radical (I) at 55 rc C enables the direct determination of rate coefficients of the hydrogen abstraction from the alcohols (II) decreasing in the order shown.
ChemInform Abstract The photochemical generation of the peroxy radical (I) at 55 rc C enables the direct determination of rate coefficients of the hydrogen abstraction from the alcohols (II) decreasing in the order shown.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.