Photochemical Oximesulfonylation of Alkenes Using Sulfonyl‐Oxime‐Ethers as Bifunctional Reagents
Jayanta Dey,
Nayan Banerjee,
Swikriti Daw
et al.
Abstract:Utilization of oxime ethers as bifunctional reagents remains unknown. Herein, we present a mechanistically distinct strategy that enables oximesulfonylation of olefins using sulfonyl‐oxime‐ethers as bifunctional reagents under metal‐free photochemical conditions. Via concomitant C‐S and C‐C bond formation, the process permits incorporation of oxime and sulfonyl groups into olefins in a complete atom‐economic fashion, providing rapid access to multi‐functionalized β‐sulfonyl oxime ethers with good yields and st… Show more
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