Photochemical degradation of fluorinated graphite stimulated by embedded nitrogen oxides

Semushkina, G. I.; Fedoseeva, Yu. V.; Макарова, Анна A.; Pinakov, D. V.; Chekhova, G. N.; Окотруб, А. В.; Bulusheva, L. G.

doi:10.1016/j.jphotochem.2023.114829

Cited by 2 publications

(1 citation statement)

References 67 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…The interaction of a molecule with a layer of fluorinated graphene determines the stability of this complex upon irradiation with light, which is important for evaluating its applicability in optical elements. Indeed, a comparison of empty C 2 F x matrices and those with nitrogen oxides in the interlayer space revealed that these guests promote the photoinduced degradation of fluorinated layers …”

Section: Introductionmentioning

confidence: 99%

Effect of Guest Molecules on Thermal Stability and Optical Characteristics of Fluorinated Graphites

Pinakov,

Chekhova,

Shubin

et al. 2023

J. Phys. Chem. C

Self Cite

View full text Add to dashboard Cite

Partially fluorinated graphites synthesized at room temperature are capable of reversibly accommodating various molecules in the interlayer space. The structures and properties of these intercalation compounds depend on the fluorine content in the matrix and the nature of the guest. In this work, we compare the thermal stability and optical characteristics of (C 2 F x ) n with x = 0.92 and 0.87, intercalated with acetonitrile and 2-butanone. Density functional theory calculations accompany experimental studies. It is shown that guest molecules prefer to be located over the sp 2 -carbon regions remaining in the partially fluorinated graphene layers. The 2-butanone molecule has stronger interactions with the layers due to its larger length, flexibility, and the presence of carbonyl oxygen. As a result, this guest leaves (C 2 F x ) n matrixes at higher temperatures than acetonitrile. Different guest−host interactions cause a change in the electron excitations and photoluminescence of the fluorinated graphite intercalation compounds. In particular, the spectra are red-shifted when the matrices contain 2-butanone. This property can be used to create optical chemisensors based on partially fluorinated graphene layers.

show abstract

Section: Introductionmentioning

confidence: 99%

Effect of Guest Molecules on Thermal Stability and Optical Characteristics of Fluorinated Graphites

Pinakov,

Chekhova,

Shubin

et al. 2023

J. Phys. Chem. C

Self Cite

View full text Add to dashboard Cite

show abstract

Surface chemistry and catalytic activity in H₂O₂ decomposition of pyrolytically fluoralkylated activated carbons

Mussabek,

Baktygerey,

Taurbayev

et al. 2024

RSC Adv.

View full text Add to dashboard Cite

show abstract

Photochemical degradation of fluorinated graphite stimulated by embedded nitrogen oxides

Cited by 2 publications

References 67 publications

Effect of Guest Molecules on Thermal Stability and Optical Characteristics of Fluorinated Graphites

Effect of Guest Molecules on Thermal Stability and Optical Characteristics of Fluorinated Graphites

Surface chemistry and catalytic activity in H₂O₂ decomposition of pyrolytically fluoralkylated activated carbons

Contact Info

Product

Resources

About

Photochemical degradation of fluorinated graphite stimulated by embedded nitrogen oxides

Cited by 2 publications

References 67 publications

Effect of Guest Molecules on Thermal Stability and Optical Characteristics of Fluorinated Graphites

Effect of Guest Molecules on Thermal Stability and Optical Characteristics of Fluorinated Graphites

Surface chemistry and catalytic activity in H2O2 decomposition of pyrolytically fluoralkylated activated carbons

Contact Info

Product

Resources

About

Surface chemistry and catalytic activity in H₂O₂ decomposition of pyrolytically fluoralkylated activated carbons