Photocatalyzed de novo synthesis of fused tetracyclic skeletons via stepwise formal [3 + 2]/[4 or 5 + 2] cycloadditions
Wenjing Guan,
Jinlin Hang,
Guanru Liu
et al.
Abstract:A visible light-promoted synthesis route to fused tetracyclic skeletons with rich sp3 carbons through stepwise radical cycloadditions and further cyclization of the final radical intermediates with adjacent aromatic rings was developed.
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