2016
DOI: 10.1002/tcr.201600008
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Photocatalytic Reduction of CO2 over Heterostructure Semiconductors into Value‐Added Chemicals

Abstract: Photoreduction of CO2 , which utilizes solar energy to convert CO2 into hydrocarbons, can be an effective means to overcome the increasing energy crisis and mitigate the rising emissions of greenhouse gas. This article covers recent advances in the CO2 photoreduction over heterostructure-based photocatalysts. The fundamentals of CO2 photoreduction and classification of the heterostructured photocatalysts are discussed first, followed by the latest work on the CO2 photoreduction over heterostructured photocatal… Show more

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Cited by 61 publications
(20 citation statements)
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“…As seen in Figure 1., the nanotubes were produced successfully by chemical treatment of commercial TiO2. At the end of the process, partially agglomerated nanotubes with diameters between 10 to 20 nm, not homogeneous in length (100-500 nm) but compatible with the literature (Guo, Wang, & He, 2016) were obtained. In Figure 2., the change in pore distribution and consequently the total surface area of commercial and nanotubes are shown.…”
Section: Resultssupporting
confidence: 86%
“…As seen in Figure 1., the nanotubes were produced successfully by chemical treatment of commercial TiO2. At the end of the process, partially agglomerated nanotubes with diameters between 10 to 20 nm, not homogeneous in length (100-500 nm) but compatible with the literature (Guo, Wang, & He, 2016) were obtained. In Figure 2., the change in pore distribution and consequently the total surface area of commercial and nanotubes are shown.…”
Section: Resultssupporting
confidence: 86%
“…Certain conditions must be met for achieving improved photocatalytic activity of semiconductor heterostructures under visible light. There exists three types of coupled heterojunctions, i.e., type-I, type-II and type-III in terms of the alignment of their energy levels (Figure 10a) [181][182][183][184][185][186]. In type-I heterostructure, the CB and VB levels of the smaller bandgap semiconductor lie between those of a wider bandgap semiconductor.…”
Section: Semiconductor Heterojunctionsmentioning
confidence: 99%
“…In terms of the alignment of the energy levels of the two semiconductors, a heterojunction can be classified into three different types: type I (straddling alignment), type II (staggered alignment), and type III (broken alignment) (Figure 8). 146 For a type I heterojunction, the conduction band (CB) and valence band (VB) levels of the larger bandgap semiconductor straddle those of the narrower bandgap semiconductor.…”
Section: Construction Of Heterostructurementioning
confidence: 99%