“…Among the vast range of methods to prepare functionalized alkenes, [2,3] hydroalkylation of alkynes [4–7] has been gaining attention as a convenient synthetic method to prepare functionalized alkenes with Markovnikov [8–11] or anti ‐Markovnikov [12–17] selectivity. In addition, functionalization of alkynes has been recently expanded by the introduction of visible light‐triggered generation of carbon‐centered radicals through a single electron transfer (SET) processes mediated by photoredox catalysts; [18] this has also been applied to the hydroalkylation of alkynes to form functionalized alkenes [6,7,9–11,13–17,19] . Indeed, both Markovnikov‐ [9–11] and anti ‐Markovnikov‐type [15,16] hydroalkylation of terminal alkynes mediated by dual photoredox and nickel catalysts has been reported, [20,21] in which alkyl carboxylic acids, [9,16] benzyl chorides, [10] cycloalkanols, [11] or dialkyl acyl peroxides [15] are used as alkylation reagents.…”