Abstract:Pollution by textile dyes on waterbodies is an issue for both human health and the environment. To remove/degrade dyes, many approaches (coagulation, membrane separation, and adsorption) have been investigated. However, the use of semiconductor-assisted materials in conjunction with sustainable solar energy has emerged as a possible solution to the problem. Although single component photocatalysts have been tested, composites of semiconductor materials are being employed owing to their low efficiency and stabi… Show more
“…The quantity of nanocomposites as nanocatalysts is another important parameter in assessing the effect of the photocatalyst process on dye removal efficiency. − The effect of the photocatalyst γ-Fe 2 O 3 Np/TiO 2 nanocomposite amount on photodegradation of OG was investigated by varying the γ-Fe 2 O 3 Np/TiO 2 amount to 50, 70, 80, 90, and 100 mg in contact with 100 mL of OG solution (5 mg L –1 ), with same experimental conditions and under LED irradiation, and the obtained results are reported in Figure . It has been observed that the loading of photocatalysts has a significant impact on OG degradation.…”
Azo dyes make up a major class of dyes that have been widely studied for their diverse applications. In this study, we successfully applied nano-γ-Fe 2 O 3 /TiO 2 as a nanocatalyst to improve the photodegradation efficiency of azo dyes (Orange G (OG) dye as a model) from aqueous solution under white lightemitting diode (LED) irradiation. We also investigated the degradation mechanisms and pathways of OG dye as well as the effects of the initial pH value, amount of H 2 O 2 , catalyst dosage, and dye concentration on the degradation processes. The characterizations of nano-γ-Fe 2 O 3 and γ-Fe 2 O 3 Nps/TiO 2 were carried out using various techniques, including X-ray diffractometry, scanning electron microscopy, energy-dispersive X-ray spectroscopy, Fourier transform infrared spectroscopy, and UV− visible spectroscopy. The efficiency of the photodegradation reaction of OG was found to follow pseudo-first-order kinetics (Langmuir−Hinshelwood model) with a rate constant of 0.0338 min −1 and an R 2 of 0.9906. Scavenger experiments revealed that hydroxyl radicals and superoxide anion radicals were the dominant species in the OG photocatalytic oxidation mechanism. This work provides a new method for designing highly efficient heterostructure-based photocatalysts (γ-Fe 2 O 3 Nps/TiO 2 ) based on LED light irradiation for environmental applications.
“…The quantity of nanocomposites as nanocatalysts is another important parameter in assessing the effect of the photocatalyst process on dye removal efficiency. − The effect of the photocatalyst γ-Fe 2 O 3 Np/TiO 2 nanocomposite amount on photodegradation of OG was investigated by varying the γ-Fe 2 O 3 Np/TiO 2 amount to 50, 70, 80, 90, and 100 mg in contact with 100 mL of OG solution (5 mg L –1 ), with same experimental conditions and under LED irradiation, and the obtained results are reported in Figure . It has been observed that the loading of photocatalysts has a significant impact on OG degradation.…”
Azo dyes make up a major class of dyes that have been widely studied for their diverse applications. In this study, we successfully applied nano-γ-Fe 2 O 3 /TiO 2 as a nanocatalyst to improve the photodegradation efficiency of azo dyes (Orange G (OG) dye as a model) from aqueous solution under white lightemitting diode (LED) irradiation. We also investigated the degradation mechanisms and pathways of OG dye as well as the effects of the initial pH value, amount of H 2 O 2 , catalyst dosage, and dye concentration on the degradation processes. The characterizations of nano-γ-Fe 2 O 3 and γ-Fe 2 O 3 Nps/TiO 2 were carried out using various techniques, including X-ray diffractometry, scanning electron microscopy, energy-dispersive X-ray spectroscopy, Fourier transform infrared spectroscopy, and UV− visible spectroscopy. The efficiency of the photodegradation reaction of OG was found to follow pseudo-first-order kinetics (Langmuir−Hinshelwood model) with a rate constant of 0.0338 min −1 and an R 2 of 0.9906. Scavenger experiments revealed that hydroxyl radicals and superoxide anion radicals were the dominant species in the OG photocatalytic oxidation mechanism. This work provides a new method for designing highly efficient heterostructure-based photocatalysts (γ-Fe 2 O 3 Nps/TiO 2 ) based on LED light irradiation for environmental applications.
“…Some of the common techniques used to characterize nanocomposites are XRD, SEM, EDS, TEM, TG, DSC, and FTIR. To investigate the phases present in the nanocomposites XRD is preferred [51][52][53][54][55]. To study the morphology of the nanocomposites SEM is the best choice.…”
The research in nanocomposites is accelerating with greater velocity due to its wide range of properties and applications in various sectors like construction, marine, automobile, aerospace, defense, and biomedical fields. Most of the researchers are trying to improve the properties further by dispersing various nanomaterials to the matrix to improve the matrix properties. In the present review article, we have discussed in brief the nanocomposites and their various synthesis routes along with their advantages and disadvantages. Why nanocomposites are more preferable over conventional composite materials is also discussed. Important characterization techniques like X-Ray diffraction (XRD), scanning electron microscope (SEM), transmission electron microscope (TEM), Fourier-transform infrared spectroscopy (FTIR), thermogravimetry (TG) and differential scanning calorimetry (DSC) used to investigate the nanocomposites are also discussed.
“…It is a persistent organic pollutant that can remain in the environment for long periods, posing a risk to aquatic life and humans. Rhodamine B is toxic to humans and can cause skin irritation, eye irritation, respiratory problems, digestive problems, and cancer [3,4]. Rhodamine B is resistant to biodegradation due to its stable structure, so it persists in natural environments and wastewater systems after use.…”
Nickel-doped manganese aluminum ferrite NiXMn1−XAl0.5Fe1.5O4 (X = 0,0.3) nanoparticles were synthesized via the Sol-gel method. XRD showed the spinel ferrite structure with average crystallite sizes of 30.66 to 39.69 nm. FTIR confirmed metal-oxygen bonds. SEM revealed the surface morphology and particle sizes of 75–95 nm. EDX confirmed the elemental composition. BET analysis determined the surface area of 13.43 m2/g for undoped and 28.38 m2/g for Ni-doped ferrite. The band gap decreases from 2.4 to 2.2 by doping nickel. Achieving 98.96% degradation of 10 mg/L Rhodamine B within 120 min under visible light irradiation was accomplished using a catalyst dose of 0.1 g/L at pH 7 and 20°C with a light intensity of 100 W. The photodegradation kinetics followed a first-order reaction. Hydroxyl radicals were identified as the major reactive species responsible for dye degradation. The nickel-doped ferrite nanoparticles exhibited efficient and stable photocatalytic performance for Rhodamine B removal from wastewater under visible light. Photocatalytic performance for Rhodamine B removal from wastewater under visible light.
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