“…Humic substance have high molecular weight naturally occurring in yellow-brown, by using TiO 2 80% humic acid reduction is reported ( Liu et al ., 2008 ), in another paper 65% reduction in humic acid reported ( Valencia et al ., 2018 ) In organic pollutant present in waste water in the form of nitrates, halides, ammonia, cyanide and thiocyanate these pollutant an effectively decompose by photocatalytic process. Different semiconductors nanoparticles such as TiO 2 against AgNO 3 , TiO ( López-Muñoz et al, 2016 , Hong et al, 2009 ) ZnO against Cr(Vi) and potassium cyanides ( Joshi and Shrivastava, 2011 , Bagabas et al, 2013 ) and CdS/Titanate nanotubes reported against ammonia in water ( Lee et al ., 2002 ).…”