Photocaging of Carboxylic Function Bearing Biomolecules by New Thiazole Derived Fluorophore
Aleksey A. Gagarin,
Artem S. Minin,
Vadim A. Shevyrin
et al.
Abstract:The design and synthesis of a new fluorophore containing an arylidene thiazole scaffold resulted in a compound with good photophysical characteristics. Furthermore, the thiazole C5‐methyl group was easily modified into specific functional groups (CH2Br and CH2OH) for the formation of a series of photocourier molecules containing model compounds (benzoic acids), as well as prodrugs, including salicylic acid, caffeic acid, and chlorambucil via a “benzyl” linker. Spectral characteristics (1Н, 13С NMR, and high‐re… Show more
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