Photo-thermal synergistic catalytic oxidative dehydrogenation of propane over a spherical superstructure of boron carbon nitride nanosheets

Yang, Dehong; Liu, Dandan; Yang, Dehong; Gan, Hongyu; Xu, Ping; Tian, Yingying; Li, Zhi; Xing, Tao; Gu, Xin; Li, Liangjun; Wang, Xuebing; Lei, Wei; Dai, Pengcheng; Wu, Mingbo

doi:10.1016/j.apsusc.2023.158258

Cited by 7 publications

(11 citation statements)

References 77 publications

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“…Utilizing thermodynamic equations to fit and analyze the acquired data, the summarized thermodynamic parameters are presented in Table S5. The equation is determined according to the following formulas: 47 = °°i k j j j j j y (7) where C e (mg/L) is the remaining concentration of Br − at equilibrium. ΔS°, ΔG°, and ΔH°represent standard entropy change, Gibbs free energy of adsorption, and the heat of the adsorption, respectively.…”

Section: ■ Results and Discussionmentioning

confidence: 99%

“…Recently, a series of metal–organic frameworks (MOFs) have emerged as highly promising materials for adsorption due to their water stability, highly tunable nature, and porous characteristics . For example, Zhang’s research group devised a boron-containing MOF with an ultrathin two-dimensional nanostructure, leveraging the synergistic enhancement of recognition capability through boron and metal coordination, achieving efficient fluoride removal .…”

Section: Introductionmentioning

confidence: 99%

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In Situ Growth of MOF from Wood Aerogel toward Bromide Ion Adsorption in Simulated Saline Water

Wang,

Yang,

et al. 2024

Langmuir

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Utilizing metal−organic framework (MOF) materials for the extraction of bromide ions (Br − ) from aqueous solutions, as an alternative to chlorine gas oxidation technology, holds promising potential for future applications. However, the limitations of powdered MOFs, such as low utilization efficiency, ease of aggregation in water, and challenging recovery processes, have hindered their practical application. Shaping MOF materials into application-oriented forms represents an effective but challenging approach to address these drawbacks. In this work, a novel Ag-UiO-66-(OH) 2 @delignified wood cellulose aerogel (CA) adsorbent is synthesized using an oil bath impregnation method, involving the deposition of UiO-66-(OH) 2 nanoparticles onto CA and the uniform dispersion of Ag 0 nanoparticles across its surface. CA, characterized by the intertwined cellulose nanofiber structure and a highly hydrophilic surface, serves as an ideal substrate for the uniform growth of UiO-66-(OH) 2 nanoparticles, which, in turn, spontaneously reduce Ag + to form distributed Ag 0 nanoparticles due to the abundant hydroxyl groups provided. Leveraging the well-defined biological structure of CA, which offers excellent mass transfer channels, and the highly dispersed Ag adsorption sites, Ag-UiO-(OH) 2 /CA exhibits remarkable adsorption capacity (642 mg/g Ag ) under optimized conditions. Furthermore, an integrated device is constructed by interconnecting Ag-UiO-(OH) 2 /CA adsorbents in series, affirming its potential application in the continuous recovery of Br − . This study not only presents an efficient Ag-UiO-(OH) 2 /CA adsorbent for Br − recovery but also sheds light on the extraction of other valuable elements from various liquid ores.

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Section: ■ Results and Discussionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

In Situ Growth of MOF from Wood Aerogel toward Bromide Ion Adsorption in Simulated Saline Water

Wang,

Yang,

et al. 2024

Langmuir

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“…Beyond the metal-based catalysts, a catalyst of semiconducting boron carbon nitride nanosheets (SS-BCNNSs) showed a propylene yield of ∼9% with a 2.5-fold increment at 450 °C after introducing light. 70 The photogenerated electrons from SS-BCNNSs promote oxygen adsorption and reduce the energy barrier for generating active B−O• species from 1.57 to 0.88 eV (Figure 5f). The increased B−O• species under light irradiation results in a decreased reaction order of reactants and activation energy, leading to enhanced propane conversion.…”

Section: Propane Dehydrogenation To Propylene (Dhp)mentioning

confidence: 99%

Section: Solar Olefins Synthesis From Dehydrogenationmentioning

confidence: 99%

Shedding Light on Solar Olefin Synthesis: Advances and Perspectives

Lu,

Wang

2024

Energy Fuels

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Light olefins, crucial feedstocks in the chemical industry, are projected to reach a market size of USD 475.8 million by 2027. Traditional methods for producing light olefins, such as cracking and the Fischer–Tropsch process, are energy-intensive and heavily reliant on fossil fuels. These production methods contribute significantly to environmental issues, emitting approximately 400 million tons of CO2 annually. Integrating solar energy into the olefin synthesis process presents a promising avenue for enhancing sustainability and efficiency. Recent research reveals the potential of utilizing solar energy to activate light-alkanes and CO x , enabling solar olefin production via dehydrogenation, hydrogenation, and reduction reactions. This review overviews recent advancements and evaluates the prospects of solar energy utilization in olefin synthesis, emphasizing innovative approaches and their potential implications.

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“…6 On the other hand, photocatalytic hydrogen production is a process of increasing Gibbs free energy. 7 Photothermal conversion materials can convert infrared light into heat, increasing the reaction temperature, reducing the reaction energy barrier 8 and improving the efficiency of hydrogen production, 9,10 as well as enabling efficient utilization of full-spectrum solar energy. Moreover, the synergy of photocatalysis and thermocatalysis due to the photothermal effect induced temperature increase can significantly improve the performance of hydrogen production, 11,12 making it promising for solar hydrogen production.…”

Section: Introductionmentioning

confidence: 99%

Photo–thermo-catalytic hydrogen production by an interfacial reactor with potassium-doped polymeric carbon nitride/titanium nitride

Wang,

Zhao,

et al. 2024

Sustainable Energy Fuels

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Photo-thermal synergistic catalytic oxidative dehydrogenation of propane over a spherical superstructure of boron carbon nitride nanosheets

Cited by 7 publications

References 77 publications

In Situ Growth of MOF from Wood Aerogel toward Bromide Ion Adsorption in Simulated Saline Water

In Situ Growth of MOF from Wood Aerogel toward Bromide Ion Adsorption in Simulated Saline Water

Shedding Light on Solar Olefin Synthesis: Advances and Perspectives

Photo–thermo-catalytic hydrogen production by an interfacial reactor with potassium-doped polymeric carbon nitride/titanium nitride

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