Photo-induced oxidation of aqueous solution of Na2[Mo(V)2O4EDTA] in neutral KBr and K2S2O8 medium

Na 2 (Mo 2 V O 4 EDTA).4H 2 O crystals have been prepared in pure form. Kinetics for the oxidation of the compound by S 2 O 8 2Ϫ have been studied spectrophotometrically in dilute sulphuric acid medium. The effects of hydrogen ion concentration, metal ion concentration, S 2 O 8 2Ϫ ion concentration, and temperature on the process have been studied. Rate equations have been derived to explain the experimental observations. On the basis of the observations, suitable mechanisms have been suggested. The kinetic parameters E*, ⌬H ϶ , and ⌬S ϶ of the process have also been determined.

show abstract

Electron transfer oxidation kinetics of Na2[Mo2O4EDTA] by S2O82? ion in dilute acid medium

Ray

Mandal

Mukherjee

1997

Int. J. Chem. Kinet.

Self Cite

View full text Add to dashboard Cite

show abstract

Molybdenum 1996

Morris

1998

Coordination Chemistry Reviews

View full text Add to dashboard Cite

scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.

Contact Info

hi@scite.ai

10624 S. Eastern Ave., Ste. A-614

Henderson, NV 89052, USA

Blog Terms and Conditions API Terms Privacy Policy Contact Cookie Preferences Do Not Sell or Share My Personal Information

Made with 💙 for researchers

Part of the Research Solutions Family.

Photo-induced oxidation of aqueous solution of Na2[Mo(V)2O4EDTA] in neutral KBr and K2S2O8 medium

Cited by 2 publications

References 14 publications

Electron transfer oxidation kinetics of Na2[Mo2O4EDTA] by S2O82? ion in dilute acid medium

Electron transfer oxidation kinetics of Na2[Mo2O4EDTA] by S2O82? ion in dilute acid medium

Molybdenum 1996

Contact Info

Product

Resources

About