Phosphotungstic acid on activated carbon: A remarkable catalyst for 5-hydroxymethylfurfural production

Costa, Nathalia Lopes da; Pereira, Lincoln Guedes; Resende, João Victor Mendes; Mendoza, Cesar D.; Ferreira, Karoline Kaiser; Detoni, Chaline; Souza, Mariana M.V.M.; Gomes, F. N. D. C.

doi:10.1016/j.mcat.2020.111334

Cited by 15 publications

(10 citation statements)

References 92 publications

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“…Recently, modified carbon-based support materials have shown notable efficiency in the catalytic production of 5-HMF starting from either fructose, glucose, cellobiose or cellulose. Various carbon-based materials, such as activated carbon [ 28 , 29 , 30 ], carbon nanotube [ 31 , 32 ], graphitic carbon nitride [ 33 , 34 ] and graphene [ 35 , 36 ], have been developed and used in heterogeneous catalysis for the production of 5-HMF starting from carbohydrate moiety such as glucose and fructose. These carbon-based materials have several advantages, such as good thermal stability, comparatively higher stability in acidic or basic media, tunable hydrophobicity and polarity, easy recovery from the reaction mixture, and cost-effectiveness compared to other conventional catalysts.…”

Section: Carbon-based Nanocatalysts For the Production Of 5-hmf From ...mentioning

confidence: 99%

Carbon-Based Nanocatalysts (CnCs) for Biomass Valorization and Hazardous Organics Remediation

et al. 2022

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The continuous increase of the demand in merchandise and fuels augments the need of modern approaches for the mass-production of renewable chemicals derived from abundant feedstocks, like biomass, as well as for the water and soil remediation pollution resulting from the anthropogenic discharge of organic compounds. Towards these directions and within the concept of circular (bio)economy, the development of efficient and sustainable catalytic processes is of paramount importance. Within this context, the design of novel catalysts play a key role, with carbon-based nanocatalysts (CnCs) representing one of the most promising class of materials. In this review, a wide range of CnCs utilized for biomass valorization towards valuable chemicals production, and for environmental remediation applications are summarized and discussed. Emphasis is given in particular on the catalytic production of 5-hydroxymethylfurfural (5-HMF) from cellulose or starch-rich food waste, the hydrogenolysis of lignin towards high bio-oil yields enriched predominately in alkyl and oxygenated phenolic monomers, the photocatalytic, sonocatalytic or sonophotocatalytic selective partial oxidation of 5-HMF to 2,5-diformylfuran (DFF) and the decomposition of organic pollutants in aqueous matrixes. The carbonaceous materials were utilized as stand-alone catalysts or as supports of (nano)metals are various types of activated micro/mesoporous carbons, graphene/graphite and the chemically modified counterparts like graphite oxide and reduced graphite oxide, carbon nanotubes, carbon quantum dots, graphitic carbon nitride, and fullerenes.

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Section: Carbon-based Nanocatalysts For the Production Of 5-hmf From ...mentioning

confidence: 99%

Carbon-Based Nanocatalysts (CnCs) for Biomass Valorization and Hazardous Organics Remediation

et al. 2022

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“…The optimal Lewis and Brønsted acid active sites on the surface for excellent catalytic performance reaction exhibited excellent glucose-to-fructose isomerization and fructoseto-HMF dehydration. 127 In a recent study from Lopes da Costa et al, 128 the HPW was synthesized as support on activated carbon (AC) for the dehydration of fructose to HMF in the DMSO solvent system. As a result, 99.3% yield of HMF and complete conversion of fructose were achieved at a reaction of 140 C for 30 minutes using 10 wt% of HPW/AC.…”

Section: Heteropolyacids (Hpas) Catalysts For Hmf Productionmentioning

confidence: 99%

“…This proved that the catalyst consists of both Lewis and Brønsted acid sites which enhanced the glucose conversion and HMF selectivity. 132 Lopes da Costa et al 128 synthesized metal supported on activated carbon (AC), where the HPW is supported on the AC (HPW/AC) catalyst, gave excellent catalytic activity for the dehydration of fructose to HMF. 128 Besides that, sulfonated oxidized activated carbon (SO 3 H-OAC) catalyst has also been stated to have excellent catalytic activity in synthesizing HMF from glucose, where almost 93% yield of HMF was acquired in a medium reaction of biphasic THF/H 2 O-NaCl solvent system.…”

Section: Other Heterogeneous Catalysts For Hmf Productionmentioning

confidence: 99%

“…132 Lopes da Costa et al 128 synthesized metal supported on activated carbon (AC), where the HPW is supported on the AC (HPW/AC) catalyst, gave excellent catalytic activity for the dehydration of fructose to HMF. 128 Besides that, sulfonated oxidized activated carbon (SO 3 H-OAC) catalyst has also been stated to have excellent catalytic activity in synthesizing HMF from glucose, where almost 93% yield of HMF was acquired in a medium reaction of biphasic THF/H 2 O-NaCl solvent system. 133 The catalyst consists of functional groups of sulfonyl hydroxide (ÀSO 3 H), hydroxyl (ÀOH), and carboxyl (ÀCOOH), which created optimal strong Brønsted base and acid sites with high specific surface area and pore volume on the surface of the AC, thus, facilitated the conversion of glucose to HMF (Table 6).…”

Section: Other Heterogeneous Catalysts For Hmf Productionmentioning

confidence: 99%

“…It can be concluded that the combination of HPW/AC catalyst and DMSO as a solvent is a promising way to synthesis HMF from fructose (Table 5). 128…”

Section: Heteropolyacids (Hpas) Catalysts For Hmf Productionmentioning

confidence: 99%

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Microporous and mesoporous structure catalysts for the production of 5‐hydroxymethylfurfural (5‐HMF)

Rani

Karim

Kamarudin

2021

Intl J of Energy Research

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In recent years, researchers have gained attention in finding new strategies for alternative renewable energy resources in reducing the dependency on fossil fuel in providing energy to the world. 5-Hydroxymethylfurfural (HMF) is one of the most promising chemicals as it is a multi-functional compound and an intermediate compound that is beneficial in numerous chemical and fuel applications. This study provides recent progress on developing high yield and selectivity of HMF using hydrothermal reaction, emphasizing the catalytic performance efficiency of the developing structured catalysts from a technical perspective. We highlighted a few critical factors and parameters in maximizing the synthesis of HMF by selectively optimizing the desired kinetic reactions, which are hydrolysis, isomerization, and dehydration of sugars, and limiting the undesired side reactions, including HMF rehydration and depolymerization. The use of different types of microporous and mesoporous catalysts provides different HMF conversion results, and by applying few parameters, including catalyst: substrate ratio, Lewis: Brønsted acid ratio, reaction temperature, and duration of reaction, can be tunable in achieving maximum HMF yield and selectivity.

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Recent reaction systems for the synthesis of 5‐hydroxymethylfurfural (HMF) from carbohydrates with process development analysis: A review

Rani

Karim

Kamarudin

2022

Intl J of Energy Research

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Summary 5‐Hydroxymethylfurfural (HMF) is a versatile biomass‐derived chemical from multifunctional compound. It is also a promising intermediate compound used in various chemical and fuel applications, including pharmaceuticals, solvents, biofuel, and other intermediates. The demand for innovative approaches to renewable energy resources has risen to diminish the dependency on petroleum‐based products and to seek economical and environmentally friendly processes for supplying energy to the world. Fructose, glucose, cellulose, and lignocellulosic materials are the most common feedstocks used to synthesize HMF. This study reviews previous studies on the development of high yield and selectivity of HMF from technical and economic perspectives. The article highlights a few significant parameters and focused on the solvent system used for the synthesis of HMF in the lab scale and through the development of process modeling using simulation software such as Aspen Plus to perform the techno‐economic analysis (TEA), which analyses the economic feasibility of the developed production process. The TEA can estimate the capital investment needed, including feedstock, catalyst, and equipment cost, and the final product's minimum selling price (MSP). HMF is cost‐efficient due to higher operational costs from the higher cost of fructose feedstock. By studying this analysis, the overall cost of HMF production can be minimized and more economically competitive with current commercial production. Besides, to make the production of HMF more cost‐effective, more research into alternative lignocellulosic feedstocks and the development of novel catalytic systems is needed.

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Phosphotungstic acid on activated carbon: A remarkable catalyst for 5-hydroxymethylfurfural production

Cited by 15 publications

References 92 publications

Carbon-Based Nanocatalysts (CnCs) for Biomass Valorization and Hazardous Organics Remediation

Carbon-Based Nanocatalysts (CnCs) for Biomass Valorization and Hazardous Organics Remediation

Microporous and mesoporous structure catalysts for the production of 5‐hydroxymethylfurfural (5‐HMF)

Recent reaction systems for the synthesis of 5‐hydroxymethylfurfural (HMF) from carbohydrates with process development analysis: A review

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