Phosphorus sustainability: a case for phytic acid as a biorenewable platform

Sperry, Jonathan; Davison, Emma K.; Neville, Jessica

doi:10.1039/d3gc01421e

Cited by 5 publications

(2 citation statements)

References 131 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…18 Annually, over 30 million metric tonnes of phytic acid are produced as agricultural waste. 19 From a structural point of view, phytic acid is known to exist as pentaequatorial (5 eq/1 ax) and pentaaxial (5 ax/1 eq) conformers (Fig. 1), where the latter is predominant at pH above 10.…”

Section: Introductionmentioning

confidence: 99%

Naturally occurring phytic acid: an advanced Brønsted acid catalyst for direct amination reactions of allylic alcohols

Pham,

Chavasiri,

Radtanajiravong

2024

Org. Biomol. Chem.

View full text Add to dashboard Cite

show abstract

Section: Introductionmentioning

confidence: 99%

Naturally occurring phytic acid: an advanced Brønsted acid catalyst for direct amination reactions of allylic alcohols

Pham,

Chavasiri,

Radtanajiravong

2024

Org. Biomol. Chem.

View full text Add to dashboard Cite

show abstract

“…Phytases are industrially important enzymes used in animal nutrition 39 . Phytases catalyze a stepwise release of phosphate from the phosphate storage compound phytate of plants 40 . Recovery of phosphate from phytate in rapeseed and other plants offers a route to green phosphate that could cover 30% of the phosphate fertilizer consumption in Germany and valorisation opportunities to flame retardant polyphosphate compounds 41 , 42 .…”

Section: Introductionmentioning

confidence: 99%

An enzymatic continuous-flow reactor based on a pore-size matching nano- and isoporous block copolymer membrane

Zhang,

Gao,

Boes

et al. 2024

Nat Commun

View full text Add to dashboard Cite

Continuous-flow biocatalysis utilizing immobilized enzymes emerged as a sustainable route for chemical synthesis. However, inadequate biocatalytic efficiency from current flow reactors, caused by non-productive enzyme immobilization or enzyme-carrier mismatches in size, hampers its widespread application. Here, we demonstrate a general-applicable and robust approach for the fabrication of a high-performance enzymatic continuous-flow reactor via integrating well-designed scalable isoporous block copolymer (BCP) membranes as carriers with an oriented and productive immobilization employing material binding peptides (MBP). Densely packed uniform enzyme-matched nanochannels of well-designed BCP membranes endow the desired nanoconfined environments towards a productive immobilized phytase. Tuning nanochannel properties can further regulate the complex reaction process and fortify the catalytic performance. The synergistic design of enzyme-matched carriers and efficient enzyme immobilization empowers an excellent catalytic performance with >1 month operational stability, superior productivity, and a high space-time yield (1.05 × 105 g L−1 d−1) via a single-pass continuous-flow process. The obtained performance makes the designed nano- and isoporous block copolymer membrane reactor highly attractive for industrial applications.

show abstract

Auto‐Optimized Electro‐Flow Reactor Platform for the in‐situ Reduction of P(V) Oxide to P(III) and Their Application

Purwa,

Chandrakanth,

Rana

et al. 2024

Chemistry An Asian Journal

View full text Add to dashboard Cite

Trivalent phosphine catalysis is mostly utilized to activate the carbon‐carbon multiple bonds to form carbanion intermediate species and highly sensitive to certain variables. Random manual multi‐variables are critical for understanding the batch disabled regeneration of trivalent phosphine chemistry. We need the artificial intelligence‐based system which can change the variable based on previously conducted failed experiment. Herein, we report an auto‐optimized electro‐micro‐flow reactor platform for the in‐situ reduction of stable P(V) oxide to sensitive P(III) and further utilized for Corey‐Fuchs reaction.

show abstract

Phosphorus sustainability: a case for phytic acid as a biorenewable platform

Abstract: Phosphorus (P) compounds play a crucial role in modern society; fertilisers, pesticides and herbicides that maintain global crop outputs and many life-saving pharmaceuticals all contain P. Most P-compounds are sourced...

Cited by 5 publications

References 131 publications

Naturally occurring phytic acid: an advanced Brønsted acid catalyst for direct amination reactions of allylic alcohols

Naturally occurring phytic acid: an advanced Brønsted acid catalyst for direct amination reactions of allylic alcohols

An enzymatic continuous-flow reactor based on a pore-size matching nano- and isoporous block copolymer membrane

Auto‐Optimized Electro‐Flow Reactor Platform for the in‐situ Reduction of P(V) Oxide to P(III) and Their Application

Contact Info

Product

Resources

About