Phosphorus–nitrogen compounds: Part V. Phenolysis of p-trichloro-n-dichlorophosphorylmonophosphazene and the crystal structure of 1-(dichlorophosphinyl)-2-chloro-2,2-bis(2,4,6-tri-tert-butylphenoxy)phosphazene

Synthesis of phenoxy‐substituted spiro‐ansa phosphazene derivatives

“…Especially, aryloxy-substituted phosphazenes are widely studied [6][7][8][9][10][11][12], but the reactions of phosphazenes with difunctional reagents are limited [13][14][15][16][17][18].…”

The reactions of hexachlorocyclotriphosphazatriene with pyridine derivatives

“…The chlorophosphazene rings, especially (PNCl 2 ) 3 (1) are important precursors of phosphazene polymers. Although a number of cyclic phosphazenes with amino [1][2][3][4][5][6][7], aryloxy [8][9][10][11][12][13], aryl [14] groups have been prepared and studied, discussion on a substitution with pyridine derivatives is relatively limited in the literature [15][16][17][18][19][20]. In this article, we report the reactions of 1 with pyridine derivatives 2-5.…”

Arylation reaction of N‐dichlorophosphoryl‐P‐trichlorophosphazene

“…The reactions of compound 1 with amines and alcohols have been reviewed [10,11]. The structures of 1 [12] and some of its derivatives, such as its pentaamide derivative (PhNH) 3 P N P(O)(NHPh) 2 [13], its geminal-bis(diisopyropylamino) derivative Cl[NCH(CH 3 ) 2 ] 2 P N P(O)Cl 2 [14], and its geminalbis(2,4,6-tert-butylphenoxide) Cl(OC 6 H 2 Bu t -2,4,6) 2 -P N P(O)Cl 2 and bis(2,6-di-tert-butyl-4-methylphenoxide) Cl(OC 6 H 2 Bu t -2,6-Me-4) 2 P N P(O)Cl 2 derivatives [15] have been reported. These molecules can be used as structural models for the inorganic polymers with a large range of properties [2,16] and applications [17][18][19][20][21][22][23][24].…”