Phosphorus(III) Chloride

Forbes, M. C.; Roswell, C. A.; Maxson, R. N.; Booth, Harold Simmons; Dolance, Albert

doi:10.1002/9780470132333.ch42

Cited by 4 publications

(2 citation statements)

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“…The classical approaches follow the same route from CS 2 to the final product (Scheme 2). The MCR approach by comparison is either 4 steps, if the route commences with phosphorus red, 26 or 3 steps if the route commences with calcium phosphate (Ca 3 (PO 4 ) 2 ) 25 (Scheme 2). The material metrics for each can be found in Table 2.…”

Section: Resultsmentioning

confidence: 99%

An evaluation of credentials of a multicomponent reaction for the synthesis of isothioureas through the use of a holistic CHEM21 green metrics toolkit

et al. 2017

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Section: Resultsmentioning

confidence: 99%

An evaluation of credentials of a multicomponent reaction for the synthesis of isothioureas through the use of a holistic CHEM21 green metrics toolkit

et al. 2017

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“…PCl 3 is commonly used as a primary source of phosphorus in organic and inorganic synthesis, especially for nucleic acids and phosphorus(III) ligands (e.g., fluorous biphase catalysts and pincer ligands), and is generally preferred over highly toxic phosphine gas, PH 3 , in organic reactions . PCl 3 is itself synthesized from elemental phosphorus and chlorine gas, and is consumed on a massive industrial scale for the synthesis of glyphosate, the highest production agricultural chemical worldwide (production since 1974 exceeding 8.6 × 10 9 kg) . Phosphorus(III) can be made to bond with three phenyl groups by the reaction of PCl 3 and chlorobenzene, yielding triphenylphosphine, a common, relatively air-stable organic reagent.…”

Section: Introductionmentioning

confidence: 99%

Bulk Phosphorus-Doped Graphitic Carbon

et al. 2018

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A direct synthetic route to a tunable range of phosphorus-doped graphitic carbon materials is demonstrated via the reaction of benzene and phosphorus trichloride in a closed reactor at elevated temperatures (800-1050 °C). Graphitic materials of continuously variable composition PCx up to a limit of approximately x = 5 are accessible, where phosphorus is incorporated both substitutionally within the graphite lattice and as stabilized P4 molecules. Higher temperatures result in a more ordered graphitic lattice while the maximum phosphorus content is not observed to diminish. Lower temperatures and higher initial phosphorus content in the reaction mixture are shown to correlate with higher structural disorder. Phosphorus incorporation within directly-synthesized PCx, as both a substitutional dopant and in the form of interstitial, stabilized molecular P4, is demonstrated to occur with little oxygen contamination in the bulk (<4 at%), motivating promising future applications in fuel cells and alkali metal-ion batteries.

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To Give Group‐VB Chlorides

Roeschenthaler¹

1989

Inorganic Reactions and Methods

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Phosphorus(III) Chloride

Cited by 4 publications

References 1 publication

An evaluation of credentials of a multicomponent reaction for the synthesis of isothioureas through the use of a holistic CHEM21 green metrics toolkit

An evaluation of credentials of a multicomponent reaction for the synthesis of isothioureas through the use of a holistic CHEM21 green metrics toolkit

Bulk Phosphorus-Doped Graphitic Carbon

To Give Group‐VB Chlorides

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