Abstract. For the first time, few-layered ReS 2 nanosheets directly nucleated and grown on the tube walls of carbon nanotubes (CNTs) have been synthesized through a facile hydrothermal method. The ReS 2 /CNTs composite delivers remarkably enhanced electrocatalytic performance. It exhibits a smaller onset overpotential of 80 mV and lower Tafel slope of 93.5 mV dec -1 than that of bare ReS 2 (100 mV, 152.7 mV dec -1 ). The unique architecture with a high conductive and porous internetwork guarantees easy electrolyte infiltration, efficient electron transfer and sufficient active edge sites, resulting in enhanced HER performance of ReS 2 /CNTs. The presented synthesis approach can be extended to synthesize other 2D-semiconductor-based composite for energy storage and catalytic devices.