Phosphorus Compounds, Inorganic

Abstract

The article contains sections titled: 1. Phosphorus ‐ Oxygen Compounds 1.1. Phosphorus Pentoxide 1.2. Other Phosphorus Oxides 1.3. Phosphorus Acids and their Salts 1.3.1. Phosphinic Acid 1.3.2. Phosphonic Acid 2. Phosphorus ‐ Halogen Compounds 2.1. Phosphorus Tri‐ and Pentahalides 2.1.1. Phosphorus Trichloride 2.1.2. Phosphorus Pentachloride 2.1.3. Phosphorus Tribromide 2.1.4. Phosphorus Fluorides 2.2. Phosphoryl and Thiophosphoryl Halides 2.2.1. Phosphoryl Chloride 2.2.2. Thiophosphoryl Chloride 3. Phosphorus Sulfides 4. Phosphides 5. Phosphorus ‐ Hydrogen Compounds 6. Phosphorus ‐ Nitrogen Compounds 7. Toxicology

Photocatalytic Arylation of P4 and PH3: Reaction Development Through Mechanistic Insight

“…Indeed, efficient, direct arylation of PH 3 remains a long‐unmet synthetic goal that, though related, is distinct from the target of direct P 4 functionalisation. [ 3c , 4 , 21 ]…”

Novel superconducting skutterudite-type phosphorus nitride at high pressure from first-principles calculations

“…Beyond the only known stable phosphorus nitride, P 3 N 5 , which forms a variety of pressure-dependent phases30313233, we find that a novel phosphorus nitride skutterudite (PN 3 ) containing six-coordinated phosphorus can be formed at undemanding pressures (~10 GPa). PN 3 is the first reported nitrogen-based skutterudite.…”

“…In this article we perform a systematic search for thermodynamically stable phosphorus nitrides under pressure using evolutionary structure prediction and density functional theory (DFT). Beyond the only known stable phosphorus nitride, P 3 N 5 , which forms a variety of pressure-dependent phases 30 31 32 33 , we find that a novel phosphorus nitride skutterudite (PN 3 ) containing six-coordinated phosphorus can be formed at undemanding pressures (~10 GPa). PN 3 is the first reported nitrogen-based skutterudite.…”

Photochemical transformation of chlorobenzenes and white phosphorus into arylphosphines and phosphonium salts

“…1a ). 1,2 Given the numerous drawbacks of this method the direct transformation of P 4 into OPCs and other P-containing compounds, avoiding potentially hazardous intermediates, has long been an exceedingly important yet challenging objective. 3 …”