Abstract:In terms of Fe 3 O 4 -based anodes, enormous academic progress has been achieved over the past two decades; however, even with excellent half-cell performance, the relatively high lithiation potential and unsatisfactory initial coulombic efficiency (ICE) represent two major barriers to their commercial application, at present. We propose partially phosphorized Fe 3 O 4 (PÀ Fe 3 O 4 ) with interior void spaces induced by phosphorization to enhance the Li + storage property of Fe 3 O 4 -based anodes. PÀ Fe 3 O 4… Show more
“…As displayed in Fig. 2(b), the photoelectron peaks centered at 710.8 and 724.6 eV are related to Fe 2+ [34], whereas the peaks located at 712.8 and 731.0 eV are attributed to Fe 3+ [22,24]. The S 2p spectrum (Fig.…”
“…As displayed in Fig. 2(b), the photoelectron peaks centered at 710.8 and 724.6 eV are related to Fe 2+ [34], whereas the peaks located at 712.8 and 731.0 eV are attributed to Fe 3+ [22,24]. The S 2p spectrum (Fig.…”
“…[4,5] Meanwhile, Li-S battery is gaining particular attention due to its excellent theoretical specific capacity (1675 mAh g À1 ) and specific energy density (2600 Wh kg À1 ), [6][7][8][9] which presents higher energy density about five times than that of conventional lithium-ion battery. [10][11][12] Thus, it has been considered as an essential breakthrough for energy storage devices.…”
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