Phonon vibrations and photoluminescence emissions and their correlations with the electrical properties in Er3+ doped Bi3YO6 oxide-ion conductors

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Current study describes the structural and magnetic properties of Ba0.9Sm0.1Fe12-xAlxO19 (x=0.0, 0.5, 1.0, 2.0, 3.0) M-type hexaferrites. Conventional ceramic route was implied to prepare all the nominal samples. Morphological analysis suggested the non-presence of secondary phases as well as formation of the hexaferrites material. X-ray Diffraction technique was used for structural analysis from which microstructural parameters are calculated and discussed. Magnetic properties are measured at room temperature. The saturation magnetization (Ms) and coercivity (Hc) values shows a cyclic and converse trend for synthesized samples. Firstly, a decrease in Ms and increase in Hc was observed up to intermediate dopant incorporation, and becomes converse for higher doping levels. The maximum coercivity and minimum magnetization is observed for Ba0.9Sm0.1Fe11Al1O19. The c/a and Mr/Ms ratio suggest the formation of perfect M-type hexaferrites. This work suggests that synthesized material is a good option for magnetic applications e.g., transformer and inductor cores, microwave devices, recording heads, and magnetic shielding.

Section: Structural Analysismentioning

confidence: 99%

Exploring the structural and magnetic trends in Ba_0.9Sm_0.1Fe_12−xAl_xO₁₉ M-type Hexaferrites

Asif¹,

Ranjha²,

Ghori³

et al. 2022

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“…Structural study is an outstanding tool that enables investigators to determine the atomic and molecular arrangement of a material, as well as its crystal structure, microstructure, and morphology. Structural analysis techniques give us significant facts on the composition, symmetry, and order of the atoms and molecules within the material [42,43]. A practical method for examining the structure of the sample is XRD.…”

Section: Structural Investigationmentioning

confidence: 99%

Effect of ferromagnetic cobalt on characteristics of coercive Aluminium substituted BaFe_11.5Al_0.5O₁₉ hexaferrites

Ijaz,

Asif,

El-Zahhar

et al. 2023

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Magnetic and structural characteristics of M-type barium hexaferrite nanoparticles can be tuned by doping different di or trivalent metal ions. Here BaFe11.5-xAl0.5CoxO19 hexaferrite nanoparticles were synthesized using a sol-gel process, and the influence of doping concentrations on M-type BaFe11.5-xAl0.5CoxO19 hexaferrite nanoparticles was deliberated. The XRD analysis confirms the formation of ferrites successfully. When the doping level increased, the grain dimension (D) initially reduced and then increased. Similarly, the lattice constants ‘a’ and ‘c’ decreased initially and then increased. The findings indicated that the (Mr/Ms) ratio decreased initially as the doping content increased, but at higher doping ranges, it started to rise. At the same time, coercivity (Hc) and magneto-crystalline an-isotropy field (Ha) increased as the doping level increased. Excellent magnetic characteristics were obtained for BaFe11.5-xAl0.5CoxO19 hexaferrites at doping content of (x=1.5), with magnetic moment 10.80µB, saturation magnetization 57.35 emu/g, and coercivity 5.21 kOe along anisotropic applied field of 1.62 kOe. The findings mentioned above imply that magnetic characteristics of M-type Barium hexaferrites can be significantly improved upon doping of Cobalt against Aluminium substituted hexaferrite, which will make such types of Ba-hexaferrite very useful in many applications, for example, in magnetic filters, memory devices, and recording media, etc.

“…Investigating the characteristics of materials structure is a crucial task that can be accomplished using structural analysis [24,32]. An X-ray diffractometer was utilized to perform XRD measurements of synthesized sample.…”

Section: Structural Analysismentioning

confidence: 99%

Structural and magnetic properties of BaFe_9.95Al₂Mg_0.05O₁₉tuned through sintering temperature

Asif,

Ranjha,

Ghori

et al. 2023

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The sintering temperature is a key way to tune the structural and magnetic properties of M-type hexaferrites. Here the effect of sintering temperature on BaFe9.95Al2Mg0.05O19 M-type hexagonal Ba-hexaferrites was studied. X-ray diffraction analysis revealed the presence of Fe2O3 impurity phases in all samples. The results showed that as the sintering temperature increased, the saturation magnetization and remanence ratio initially increased, then decreased at higher temperatures. On the other hand, the coercivity and magnetocrystalline anisotropy field decreased first, then increased. The morphology suggested that average grain size consistently grew between 800-2800 nm with increasing temperature. The optimal magnetic properties of BaFe9.95Al2Mg0.05O19 were achieved at a sintering temperature of 1280 ℃, with saturation magnetization 49.94 emu/g, coercivity 4.99 kOe, anisotropic field 1.5kOe, and magnetic moment of 9.4097µB. The findings suggest that the magnetic properties of M-type hexagonal ferrites can be significantly enhanced by optimizing the sintering temperature, which has implications for the development of high-performance self-biased circulators, Magnetic filters, and other magnetic applications.