The dependence of T c on hydrostatic (He-gas) pressure for superconducting MgB 2 has been determined to 0.7 GPa. We find that T c decreases linearly and reversibly under pressure at the rate dT c /dP ≃ −1.11 ± 0.02 K/GPa. These studies were carried out on the same sample used in earlier structural studies under He-gas pressure which yielded the bulk modulus B = 147.2 ± 0.7 GPa. The value of the logarithmic volume derivative of T c is thus accurately determined, d ln T c /d ln V = +4.16 ± 0.08, allowing quantitative comparison with theory. The present results support the emerging picture that MgB 2 is a BCS superconductor with electron-phonon pairing interaction.
1The recent discovery [1] of superconductivity in MgB 2 at T c ≃ 39 K has sparked worldwide a torrent of experimental and theoretical activity, reminiscent of the frenzy following the observation [2] of superconductivity in La-Ba-Cu-O at a comparable temperature almost 15 years ago. Replacing 10 B with 11 B results in a sizeable isotope shift [3] to lower temperatures which points to BCS superconductivity. Other experiments, such as heat capacity [4,5], photoemission spectroscopy [6], and inelastic neutron scattering [7,8] also support the picture that MgB 2 is a phonon-mediated superconductor in the weak-to-moderate coupling regime.High pressure studies traditionally play an important role in superconductivity. A large magnitude of the pressure derivative dT c /dP is a good indication that higher values of T c may be obtained through chemical means. It is not widely appreciated, however, that the pressure dependence T c (P ), like the isotope effect, contains valuable information on the superconducting mechanism itself. For example, in simple-metal BCS superconductors, like Al, In, Sn, and Pb, T c invariably decreases under pressure due to the reduced electron-phonon coupling from lattice stiffening [9]. More generally, an accurate determination of the dependence of both T c and the lattice parameters on pressure yields the functional dependence T c = T c [a(P ), b(P ), c(P )] which provides a critical test of theoretical models. Hirsch [10] and Hirsch and Marsiglio [11] have applied a theory of hole superconductivity to MgB 2 and predicted that for an optimally doped sample T c should increase with pressure, in contrast to the expected decrease in T c from lattice stiffening.Precise structural data on MgB 2 at room temperature (RT) have recently been obtained by Jorgensen et al.[12] for hydrostatic pressures to 0.6 GPa in a He-gas neutron diffraction facility which yield the anisotropic compressibilities d ln a/dP = −1.87 × 10 −3 GPa −1 , d ln b/dP = −3.07 × 10 −3 GPa −1 , and the bulk modulus B = 147.2 ± 0.7 GPa; the compressibility along the c axis is thus significantly (64%) larger than that along the a axis. The binding within the boron layers is evidently much stronger than between the layers. These results are in reasonable agreement with electronic structure calculations by Loa and Syassen [13].Recent synchrotron x-ray diffraction studi...