Abstract. Mixed-phase Southern Ocean clouds are challenging to simulate, and their
representation in climate models is an important control on climate
sensitivity. In particular, the amount of supercooled water and frozen mass
that they contain in the present climate is a predictor of their planetary
feedback in a warming climate. The recent Southern Ocean Clouds, Radiation, Aerosol Transport Experimental Study (SOCRATES) vastly increased the
amount of in situ data available from mixed-phase Southern Ocean clouds useful
for model evaluation. Bulk measurements distinguishing liquid and ice water
content are not available from SOCRATES, so single-particle phase
classifications from the Two-Dimensional Stereo (2D-S) probe are invaluable
for quantifying mixed-phase cloud properties. Motivated by the presence of
large biases in existing phase discrimination algorithms, we develop a novel
technique for single-particle phase classification of binary 2D-S images using
a random forest algorithm, which we refer to as the University of Washington
Ice–Liquid Discriminator (UWILD). UWILD uses 14 parameters computed from
binary image data, as well as particle inter-arrival time, to predict phase.
We use liquid-only and ice-dominated time periods within the SOCRATES dataset
as training and testing data. This novel approach to model training avoids
major pitfalls associated with using manually labeled data, including reduced
model generalizability and high labor costs. We find that UWILD is well
calibrated and has an overall accuracy of 95 % compared to
72 % and 79 % for two existing phase classification
algorithms that we compare it with. UWILD improves classifications of small
ice crystals and large liquid drops in particular and has more flexibility
than the other algorithms to identify both liquid-dominated and ice-dominated
regions within the SOCRATES dataset. UWILD misclassifies a small percentage
of large liquid drops as ice. Such misclassified particles are typically
associated with model confidence below 75 % and can easily be
filtered out of the dataset. UWILD phase classifications show that particles
with area-equivalent diameter (Deq) < 0.17 mm are mostly
liquid at all temperatures sampled, down to −40 ∘C. Larger
particles (Deq>0.17 mm) are predominantly frozen at all
temperatures below 0 ∘C. Between 0 and 5 ∘C,
there are roughly equal numbers of frozen and liquid mid-sized particles (0.17<Deq<0.33 mm), and larger particles (Deq>0.33 mm) are mostly frozen. We also use UWILD's phase
classifications to estimate sub-1 Hz phase heterogeneity, and we show
examples of meter-scale cloud phase heterogeneity in the SOCRATES dataset.