Phenylcyanamide Ligands

Crutchley, Robert J.

doi:10.1016/b0-08-043748-6/01112-9

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Synthetic Applications Of Substituted Cyanamides1

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Cited by 3 publications

(2 citation statements)

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“…In addition, the mono-substituted cyanamides, such as phenylcyanamide (PhNHCN) are known to participate as coordinating ligands in neutral as well as anionic cyanamido form ([PNCN] − ) [ 72 ].…”

Section: Synthetic Applications Of Substituted Cyanamidesmentioning

confidence: 99%

Recent Advances in Cyanamide Chemistry: Synthesis and Applications

et al. 2017

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Section: Synthetic Applications Of Substituted Cyanamidesmentioning

confidence: 99%

Recent Advances in Cyanamide Chemistry: Synthesis and Applications

et al. 2017

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“…One should mention that a good number of various cyanamides, whose intriguing chemistry is at the early stage of development although they become increasingly popular in recent years, are commercially available. Moreover, disubstituted cyanamides can be easily prepared from amines R 2 R 3 NH and potassium or sodium cyanate followed by dehydration in the presence of p -TsCl in pyridine .…”

mentioning

confidence: 99%

Facile Gold-Catalyzed Heterocyclization of Terminal Alkynes and Cyanamides Leading to Substituted 2-Amino-1,3-Oxazoles

2015

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Facile gold-catalyzed heterocyclization based upon intermolecular trapping of the generated α-oxo gold carbenes with various cyanamides R(2)R(3)NCN (R(2)/R(3) = Alk/Alk, -(CH2)2O(CH2)2-, Ar/Ar, Ar/H) has been developed. In most cases, 2-amino-1,3-oxazoles functionalized at the nitrogen atom as well as at the fifth position of the heterocyclic ring (12 examples) were isolated in good to moderate yields.

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