Phenoxo bridged luminescent dinuclear zinc(II) and cadmium(II) complexes of 2-[[[2-(2-pyridyl)ethyl]imino]methyl]phenol: Crystal structure, photophysical and thermal studies

Mono, di and trinuclear photo-luminescent cadmium(II) complexes with N2O and N2O2 donor salicylidimine Schiff bases: Synthesis, structure and self assembly

“…The chemistry of the metal Schiff base complexes has been paid considerable attention since long and it is still a promising area of research [1][2][3][4][5][6][7][8][9][10]. Among different Schiff bases, N 2 O donor salicylidimine Schiff bases [11][12][13], have widely been used by several groups to form different homo and hetero polynuclear complexes with several transition and non-transition metal ions [14][15][16][17][18][19][20].…”

Coordinating and non-coordinating anion controlled synthesis of different nuclearity cadmium(II) complexes of 2-((E)-((pyridin-2-yl)methylimino)methyl)phenol: Crystal structure and photophysical study

“…In one of our earlier studies [20] we observed that the Schiff-base formed by binding mode [28,29]. On the other hand, the IR band centered at ~ 2200 cm -1 in complex 3 has been assigned to the coordinated dca anion.…”

“…Actually the geometry of cadmium complexes results from a balance between the bonding energies and repulsion amongst ligands [20]. Recently we reported the coligand mediated photophysical behavior and catalytic activity of a series of zinc(II) complexes of a potential N,N,O-donor tridentate Schiff-base ligand, 2-((E)-((pyridin-2-yl)methylimino)methyl)phenol (HL), with Cl -, Br -, OAc -and SCN -as co-ligands.…”

Two cadmium(II) complexes with oxazoline-based ligands as effective catalysts for C–N cross-coupling reactions

“…The equatorial Cd-Cl bonds (2.6235(6) Å and 2.5318(6) Å) are longer than the axial (2.4230(6) Å). The bond length of N-Cd are 2.3962(16) Å and 2.4230(6) Å, respectively, which is slightly longer than those observed in the [Cd 2 L 2 X 2 ] (X = Cl, Br, I) [36] and [Cd(1-tza)(phen)(NO 3 )] (1-tza = tetrazole-1-acetic acid) [37]. As seen in Fig.…”