Phenoxazinyl Zn(<scp>ii</scp>) diradical complex formed via redox-driven cyclization of a 2-aminophenol-based N3O ligand. Isolation of the modified N3 ligand radical and its Ni(<scp>ii</scp>) complex

Mukhopadhyay, Narottam; Sengupta, Arunava; Lloret, Francesc; Mukherjee, Rabindranath

doi:10.1039/d4dt00374h

Dalton Trans.

2024

DOI: 10.1039/d4dt00374h

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Phenoxazinyl Zn(ii) diradical complex formed via redox-driven cyclization of a 2-aminophenol-based N₃O ligand. Isolation of the modified N₃ ligand radical and its Ni(ii) complex

Narottam Mukhopadhyay,

Arunava Sengupta,

Francesc Lloret

et al.

Abstract: Intramolecular cyclization of an N3O ligand in air affording a phenoxazinyl Zn(ii) diradical complex and isolation of the modified N3 ligand-radical.

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Cited by 2 publications

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Chemical fixation of atmospheric CO₂ in tricopper(ii)-carbonato complexes with tetradentate N-donor ligands: reactive intermediates, probable mechanisms, and catalytic and magneto-structural studies

Jana,

Sun,

Herchel

et al. 2024

Dalton Trans.

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Chemical fixation of atmospheric CO₂ in tricopper(ii)-carbonato complexes with tetradentate N-donor ligands: reactive intermediates, probable mechanisms, and catalytic and magneto-structural studies

Jana,

Sun,

Herchel

et al. 2024

Dalton Trans.

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Ni(ii) and Pd(ii) complexes of a new redox-active pentadentate azo-appended 2-aminophenol ligand: Pd(ii)-assisted intraligand cyclization forms a phenoxazinyl ring

Bhowmik,

Sengupta,

Mukherjee

2024

Dalton Trans.

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Phenoxazinyl Zn(ii) diradical complex formed via redox-driven cyclization of a 2-aminophenol-based N₃O ligand. Isolation of the modified N₃ ligand radical and its Ni(ii) complex

Abstract: Intramolecular cyclization of an N3O ligand in air affording a phenoxazinyl Zn(ii) diradical complex and isolation of the modified N3 ligand-radical.

Cited by 2 publications

References 43 publications

Chemical fixation of atmospheric CO₂ in tricopper(ii)-carbonato complexes with tetradentate N-donor ligands: reactive intermediates, probable mechanisms, and catalytic and magneto-structural studies

Chemical fixation of atmospheric CO₂ in tricopper(ii)-carbonato complexes with tetradentate N-donor ligands: reactive intermediates, probable mechanisms, and catalytic and magneto-structural studies

Ni(ii) and Pd(ii) complexes of a new redox-active pentadentate azo-appended 2-aminophenol ligand: Pd(ii)-assisted intraligand cyclization forms a phenoxazinyl ring

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Phenoxazinyl Zn(ii) diradical complex formed via redox-driven cyclization of a 2-aminophenol-based N3O ligand. Isolation of the modified N3 ligand radical and its Ni(ii) complex

Abstract: Intramolecular cyclization of an N3O ligand in air affording a phenoxazinyl Zn(ii) diradical complex and isolation of the modified N3 ligand-radical.

Cited by 2 publications

References 43 publications

Chemical fixation of atmospheric CO2 in tricopper(ii)-carbonato complexes with tetradentate N-donor ligands: reactive intermediates, probable mechanisms, and catalytic and magneto-structural studies

Chemical fixation of atmospheric CO2 in tricopper(ii)-carbonato complexes with tetradentate N-donor ligands: reactive intermediates, probable mechanisms, and catalytic and magneto-structural studies

Ni(ii) and Pd(ii) complexes of a new redox-active pentadentate azo-appended 2-aminophenol ligand: Pd(ii)-assisted intraligand cyclization forms a phenoxazinyl ring

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Phenoxazinyl Zn(ii) diradical complex formed via redox-driven cyclization of a 2-aminophenol-based N₃O ligand. Isolation of the modified N₃ ligand radical and its Ni(ii) complex

Chemical fixation of atmospheric CO₂ in tricopper(ii)-carbonato complexes with tetradentate N-donor ligands: reactive intermediates, probable mechanisms, and catalytic and magneto-structural studies

Chemical fixation of atmospheric CO₂ in tricopper(ii)-carbonato complexes with tetradentate N-donor ligands: reactive intermediates, probable mechanisms, and catalytic and magneto-structural studies