1999
DOI: 10.1021/jf990009o
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Phenolic Compounds in Spanish Olive Oils

Abstract: Phenolic compounds in Spanish virgin olive oils were characterized by HPLC. Simple phenols such as hydroxytyrosol, tyrosol, vanillic acid, p-coumaric acid, ferulic acid, and vanillin were found in most of the oils. The flavonoids apigenin and luteolin were also found in most of the oils. The dialdehydic form of elenolic acid linked to tyrosol and hydroxytyrosol was also detected, as were oleuropein and ligstroside aglycons. The structure of a new compound was elucidated by MS and NMR as being that of 4-(acetox… Show more

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Cited by 329 publications
(311 citation statements)
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References 17 publications
(26 reference statements)
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“…By considering only the ripeness, a maximum value of their concentration is observed in oils from the first stage; it decreased gradually in the oil extracted from healthy olives as ripening degree advanced. This loss, in relation to samples S 1 , in agreement with results of Brenes et al (1999); Gutierrez et al, (1999) Table 2 Analytical characteristics of the oils produced at different olive sampling times (mean The attack on olives by B. oleae caused important losses in the total amount of phenolic compounds, particularly in oils from olives in advanced stages of ripeness. The reduction of the phenolic concentration in oils from olives totally attacked at stages 1, 2 and 3, in relation to corresponding samples from healthy fruits, was about 34, 46 and 49 % respectively.…”
Section: Total Phenolic Compoundssupporting
confidence: 83%
See 1 more Smart Citation
“…By considering only the ripeness, a maximum value of their concentration is observed in oils from the first stage; it decreased gradually in the oil extracted from healthy olives as ripening degree advanced. This loss, in relation to samples S 1 , in agreement with results of Brenes et al (1999); Gutierrez et al, (1999) Table 2 Analytical characteristics of the oils produced at different olive sampling times (mean The attack on olives by B. oleae caused important losses in the total amount of phenolic compounds, particularly in oils from olives in advanced stages of ripeness. The reduction of the phenolic concentration in oils from olives totally attacked at stages 1, 2 and 3, in relation to corresponding samples from healthy fruits, was about 34, 46 and 49 % respectively.…”
Section: Total Phenolic Compoundssupporting
confidence: 83%
“…Tyrosol and Hydroxytyrosol tended to increase with maturation. On the contrary, both the dialdehydic form and elenolic acid linked to tyrosol or hydroxytyrosol and the oleuropein or ligstroside GRASAS Y ACEITES, 60 (5), OCTUBRE-DICIEMBRE, 507-513, 2009 (Brenes et al, 1999). Studies concerning the simultaneous action of maturity and the attack by B. Oleae on oil quality and phenolic compounds do not exist.…”
Section: Introductionmentioning
confidence: 99%
“…Table 2 provides an overview of methodologies based on LC-tandem mass spectrometry used for the analysis of phenolic compounds in olive oil. The table does not include several publications in which the analysis of olive fruit, leaves, pulp and pomace, olive tree wood, as well as olive oil waste waters were carried out by using HPLC-MS [14,49,156,[161][162][163][164][165][166][167][168]. Other important issues are the presence of phenolic metabolites of VOO in the human low density lipoprotein fraction [169][170].…”
Section: New Analytical Approaches To Characterization Of the Phenolimentioning
confidence: 99%
“…Flavonoid aglycones are subdivided into flavones, flavonols, flavanones, and flavanols depending upon the presence of a carbonyl carbon at C-4, an OH group at C-3, a saturated single bond between C-2 and C-3, and a combination of no carbonyl at C-4 with an OH group at C-3, respectively. Several authors have reported that flavonoids such as luteolin and apigenin are also phenolic components of VOO [41][42][43][44][45][46]. Luteolin may originate from rutin or luteolin-7-glucoside, and apigenin from apigenin glucosides.…”
mentioning
confidence: 99%
“…Vanillin is naturally obtained from vanilla beans, however, the beans are expensive; therefore, the compound is either extracted from lignin waste or from eugenol (a readily available ingredient) or guaiacol. Lignin-based vanillin is said to have a richer flavor profile than oilbased flavoring mainly due to the presence of acetovanillone in the lignin-derived product [9]. Production of vanillin from guaiacol is synthesized through electrophilic aromation substitution on reaction with glycoxylic acid; which results in synthesis of vanillylmandelic acid which is then converted 4-hydroxy-3-methoxyphenylglyoxylic acid and vanillin by oxidative decarboxylation [10].…”
Section: Introductionmentioning
confidence: 99%