Phasenumwandlungen im System Kupfer—Antimon

Boettcher, A.; Thun, R.

doi:10.1002/zaac.19562830106

Cited by 13 publications

(12 citation statements)

References 5 publications

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“…[8][9][10] The idea of utilizing deliberately created composition gradients in co-deposited thin films to obtain significant portions of phase diagrams can be traced back to about fifty years ago for various ternary systems. [11][12][13][14] In this review, we concentrate on applications of combinatorial materials science for electronic, magnetic, optical, and energy-related materials. As the emphasis of this review is on applications of these functional materials, 15,16 library synthesis techniques, and properties measurement and analysis methods, are only covered as they apply to the materials of interest.…”

Section: Applied Physics Reviews-focused Reviewmentioning

confidence: 99%

Applications of high throughput (combinatorial) methodologies to electronic, magnetic, optical, and energy-related materials

Green

Takeuchi

Hattrick‐Simpers

2013

Journal of Applied Physics

224

189

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High throughput (combinatorial) materials science methodology is a relatively new research paradigm that offers the promise of rapid and efficient materials screening, optimization, and discovery. The paradigm started in the pharmaceutical industry but was rapidly adopted to accelerate materials research in a wide variety of areas. High throughput experiments are characterized by synthesis of a "library" sample that contains the materials variation of interest (typically composition), and rapid and localized measurement schemes that result in massive data sets. Because the data are collected at the same time on the same "library" sample, they can be highly uniform with respect to fixed processing parameters. This article critically reviews the literature pertaining to applications of combinatorial materials science for electronic, magnetic, optical, and energy-related materials. It is expected that high throughput methodologies will facilitate commercialization of novel materials for these critically important applications. Despite the overwhelming evidence presented in this paper that high throughput studies can effectively inform commercial practice, in our perception, it remains an underutilized research and development tool. Part of this perception may be due to the inaccessibility of proprietary industrial research and development practices, but clearly the initial cost and availability of high throughput laboratory equipment plays a role. Combinatorial materials science has traditionally been focused on materials discovery, screening, and optimization to combat the extremely high cost and long development times for new materials and their introduction into commerce. Going forward, combinatorial materials science will also be driven by other needs such as materials substitution and experimental verification of materials properties predicted by modeling and simulation, which have recently received much attention with the advent of the Materials Genome Initiative. Thus, the challenge for combinatorial methodology will be the effective coupling of synthesis, characterization and theory, and the ability to rapidly manage large amounts of data in a variety of formats. V C 2013 AIP Publishing LLC. [http://dx

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Section: Applied Physics Reviews-focused Reviewmentioning

confidence: 99%

Applications of high throughput (combinatorial) methodologies to electronic, magnetic, optical, and energy-related materials

Green

Takeuchi

Hattrick‐Simpers

2013

Journal of Applied Physics

224

189

View full text Add to dashboard Cite

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“…A number of the early combinatorial attempts involved thin films. In 1955, Boettcher et al [ 6 ] deposited thin films with composition gradients and used electron diffraction to identify existing phases for constructing phase diagrams. They tested the methodology on the Ag-Sn and Au-Sn binary systems, and then applied the methodology to map the phase diagram of the Ag-Pb-Sn ternary isothermal section.…”

Section: Combinatorial Methods For Construction Of Phase Diagramsmentioning

confidence: 99%

“…The state-of-the-art combinatorial methods [ 9 – 11 ] follow the same general concepts introduced by Boettcher et al [ 6 ] and Kennedy et al [ 8 ]. Currently, three techniques are commonly used to create thin film combinatorial libraries.…”

Section: Combinatorial Methods For Construction Of Phase Diagramsmentioning

confidence: 99%

“…According to Zhao [ 5 ], attempts to accelerate phase diagram studies combinatorially can be traced back at least half a century ago. In 1955, Boettcher et al [ 6 ] designed and deposited thin films with composition gradients, and used electron diffraction to identify phases, in order to construct a phase diagram of the Ag-Pb-Sn system. A decade later, Kennedy et al [ 7 , 8 ] used a similar approach to map the Cr-Fe-Ni ternary phase diagram.…”

Section: Introductionmentioning

confidence: 99%

See 1 more Smart Citation

Evaluation of the Current Status of the Combinatorial Approach for the Study of Phase Diagrams

Wong‐Ng¹

2012

J. RES. NATL. INST. STAN.

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This paper provides an evaluation of the effectiveness of using the high throughput combinatorial approach for preparing phase diagrams of thin film and bulk materials. Our evaluation is based primarily on examples of combinatorial phase diagrams that have been reported in the literature as well as based on our own laboratory experiments. Various factors that affect the construction of these phase diagrams are examined. Instrumentation and analytical approaches needed to improve data acquisition and data analysis are summarized.

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“…Computational density of states calculations have shown how the band structure of TiO 2 consists of a valence band made primarily of O 2p orbitals and a conduction band made primarily of Ti 3d orbitals. TiO 2 thin films have been doped with a range of non‐metals such as boron,56 carbon,45 nitrogen,5 fluorine,57 phosphorus,58 and sulfur42 in order to alter the band structure. These dopants typically substitute oxygen (O 2− ) sites, but can also enter interstitially within the titanium‐oxygen framework.…”

Section: Introductionmentioning

confidence: 99%

CVD Production of Doped Titanium Dioxide Thin Films

Dunnill

Kafizas

Parkin

2012

Chemical Vapor Deposition

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This review focuses on the formation of doped titanium dioxide films by CVD. It describes a number of the functional applications of titanium dioxide films, and illustrates how these properties can be improved or modified by the introduction of anion and cation dopants. It details some of the underlying theory and looks at how density of states diagrams can be used to explain the doped film properties.

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Phasenumwandlungen im System Kupfer—Antimon

Cited by 13 publications

References 5 publications

Applications of high throughput (combinatorial) methodologies to electronic, magnetic, optical, and energy-related materials

Applications of high throughput (combinatorial) methodologies to electronic, magnetic, optical, and energy-related materials

Evaluation of the Current Status of the Combinatorial Approach for the Study of Phase Diagrams

CVD Production of Doped Titanium Dioxide Thin Films

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