Phase transformations in a double complex salt of the ruthenium nitrosyl anion and tetraamine-palladium cation

Abstract

A reversible order–disorder phase transition in [Pd(NH3)4][RuNO(NO2)4OH] in the temperature range of 370–390 K was confirmed by DSC, single crystal and powder diffraction data.

Ruthenium-nitrosyl complexes as NO-releasing molecules, potential anticancer drugs, and photoswitches based on linkage isomerism

“…These complexes were prepared by reaction of Na 2 [RuNO(NO 2 ) 4 OH] with [Pd(L) 4 ](NO 3 ) 2 . 108,109 In the case of [Pd(NH 3 ) 4 ][RuNO(NO 2 ) 4 OH], the palladium and ruthenium subunits are bound by hydrogen bonds between NH 3 and NO 2 − ligands (Fig. 4).…”

[NiEn3](MoO4)0.5(WO4)0.5 Co-Crystals as Single-Source Precursors for Ternary Refractory Ni–Mo–W Alloys

“…The low-temperature preparation of binary alloys from single-source precursors has been studied in a large number of works in the last decade [1][2][3][4][5][6][7][8][9][10][11][12][13][14][15][16][17][18]. Binary alloys can be prepared for a large variety of refractory metals including Pt, Pd, Ir, Rh, and Os.…”